| 234 | IL Philip | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 191 | HG Munsey | Scotland v Netherlands | Forthill, Dundee | 2025 |
| 190* | J Aitchison | Scotland v Ireland | College Park, Dublin | 1959 |
| 181 | G Salmond | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 181 | NFI McCallum | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 178* | J Kerr | Scotland v Ireland | College Park, Dublin | 1923 |
| 175 | CS MacLeod | Scotland v Canada | Hagley Oval, Christchurch | 2013/14 |
| 171* | DF Watts | Scotland v Denmark | New Anniesland, Glasgow | 2006 |
| 167 | RR Watson | Scotland v Namibia | Mannofield Park, Aberdeen | 2006 |
| 161 | LC Dudman | Scotland v Warwickshire | Edgbaston, Birmingham | 1956 |
| 157* | CS MacLeod | Scotland v Afghanistan | Bulawayo Athletic Club, Bulawayo | 2017/18 |
| 156 | KJ Coetzer | Scotland v Bangladesh | Saxton Oval, Nelson | 2014/15 |
| 154 | RR Watson | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 154 | CS MacLeod | Scotland v Papua New Guinea | Amini Park, Port Moresby | 2017/18 |
| 153* | IL Philip | Scotland v England Amateur XI | Osborne Avenue, Jesmond | 1991 |
| 153* | GN Reifer | Scotland v Transvaal University | Eben Cuyler Park, Johannesburg | 1991/92 |
| 151 | DR Lockhart | Scotland v Canada | Maple Leaf North-East Ground, King City | 2008 |
| 151 | B McMullen | Scotland v United States of America | Grand Prairie Stadium, Grand Prairie | 2024/25 |
| 150 | J Aitchison | Scotland v Yorkshire | Hamilton Crescent, Glasgow | 1952 |
| 147 | J Kerr | Scotland v Australians | Raeburn Place, Edinburgh | 1921 |
| 146 | DF Watts | Scotland v Kenya | Sheikh Zayed Stadium, Abu Dhabi | 2004/05 |
| 145 | IL Philip | Scotland v Ireland | Titwood, Glasgow | 1986 |
| 145 | CS MacLeod | Scotland v Netherlands | Titwood, Glasgow | 2014 |
| 144* | GL Willatt | Scotland v Warwickshire | Mannofield Park, Aberdeen | 1949 |
| 143* | BR Tod | Scotland v Ireland | Raeburn Place, Edinburgh | 1936 |
| 143 | HK More | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1969 |
| 142 | WA Donald | Scotland v Marylebone Cricket Club | North Inch, Perth | 1981 |
| 140* | CS MacLeod | Scotland v England | Raeburn Place, Edinburgh | 2018 |
| 139* | W Nichol | Scotland v Warwickshire | Edgbaston, Birmingham | 1951 |
| 139* | PL Mommsen | Scotland v United Arab Emirates | Bert Sutcliffe Oval, Lincoln | 2013/14 |
| 137 | J Kerr | Scotland v Ireland | Glenpark, Greenock | 1926 |
| 137 | J Kerr | Scotland v Ireland | Raeburn Place, Edinburgh | 1928 |
| 136 | J Kerr | Scotland v Ireland | College Park, Dublin | 1927 |
| 136 | GWA Alexander | Scotland v Ireland | Mannofield Park, Aberdeen | 1930 |
| 136 | B McMullen | Scotland v Oman | Bulawayo Athletic Club, Bulawayo | 2023 |
| 134 | HK More | Scotland v Warwickshire | Edgbaston, Birmingham | 1974 |
| 134 | IL Philip | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1997 |
| 133* | KJ Coetzer | Scotland v Kenya | Sheikh Zayed Stadium, Abu Dhabi | 2004/05 |
| 133 | KJ Coetzer | Scotland v Afghanistan | Sharjah Cricket Association Stadium, Sharjah | 2012/13 |
| 133* | CS MacLeod | Scotland v United States of America | Mannofield Park, Aberdeen | 2022 |
| 132 | DBS Brown | Scotland v Wales | Forthill, Dundee | 1976 |
| 132 | HG Munsey | Scotland v Austria | Goldenacre, Edinburgh | 2023 |
| 131 | GM Hamilton | Scotland v Leicestershire | Raeburn Place, Edinburgh | 2006 |
| 129 | H Wass | Scotland v Sir J Cahn's XI | West Park, West Bridgford | 1937 |
| 129* | RS Dravid | Scotland v Nottinghamshire | Raeburn Place, Edinburgh | 2003 |
| 129 | RD Berrington | Scotland v Papua New Guinea | Amini Park, Port Moresby | 2017/18 |
| 127* | JR Laing | Scotland v Ireland | Hamilton Crescent, Glasgow | 1976 |
| 127 | KJ Coetzer | Scotland v Oman | Walter Milton Oval, University of Witwatersrand, Johannesburg | 2008/09 |
| 127 | GM Hamilton | Scotland v United Arab Emirates | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 127 | KJ Coetzer | Scotland v United Arab Emirates | Raeburn Place, Edinburgh | 2016 |
| 127* | HG Munsey | Scotland v Netherlands | The Village, Malahide, Dublin | 2019 |
| 127 | RD Berrington | Scotland v United Arab Emirates | Bulawayo Athletic Club, Bulawayo | 2023 |
| 127* | OJ Hairs | Scotland v Italy | Raeburn Place, Edinburgh | 2023 |
| 125 | TB Racionzer | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1977 |
| 125 | TB Racionzer | Scotland v Netherlands | Hamilton Crescent, Glasgow | 1980 |
| 124 | TB Racionzer | Scotland v Warwickshire | Edgbaston, Birmingham | 1976 |
| 123* | RR Watson | Scotland v Canada | Mombasa Sports Club Ground, Mombasa | 2006/07 |
| 123* | GJ Bailey | Scotland v Warwickshire | Edgbaston, Birmingham | 2010 |
| 122 | JB Jones | Scotland v Sir J Cahn's XI | Stanford Hall, Stanford | 1935 |
| 122 | KJ Coetzer | Scotland v Northamptonshire | Raeburn Place, Edinburgh | 2011 |
| 121 | JD Henderson | Scotland v Ireland | Whitehaugh Oval, Paisley | 1954 |
| 121* | IL Philip | Scotland v England Amateur XI | Raeburn Place, Edinburgh | 1992 |
| 121 | IL Philip | Scotland v Ireland | Main Road, Ynysygerwn | 1996 |
| 121* | NFI McCallum | Scotland v Ireland | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 121 | KJ Coetzer | Scotland v Kenya | Dubai Sports City Stadium, Dubai | 2017/18 |
| 120* | RS Dravid | Scotland v Somerset | County Ground, Taunton | 2003 |
| 120* | RM Haq | Scotland v Netherlands | Mannofield Park, Aberdeen | 2011 |
| 119* | DR Lockhart | Scotland v Earl of Arundel's XI | Arundel Castle Cricket Club Ground, Arundel | 1996 |
| 119 | GM Hamilton | Scotland v Canada | Mannofield Park, Aberdeen | 2009 |
| 118 | BR Hardie | Scotland v Warwickshire | Edgbaston, Birmingham | 1970 |
| 118 | BR Hardie | Scotland v Warwickshire | Edgbaston, Birmingham | 1972 |
| 118 | BR Hardie | Scotland v Warwickshire | Edgbaston, Birmingham | 1974 |
| 118 | G Salmond | Scotland v Ireland | Forthill, Dundee | 1992 |
| 118* | DF Watts | Scotland v Ireland | Castle Avenue, Dublin | 2004 |
| 118 | PL Mommsen | Scotland v Hong Kong | Queenstown Events Centre, Queenstown | 2013/14 |
| 118 | KJ Coetzer | Scotland v Sri Lanka | The Kent County Cricket Ground, Beckenham | 2017 |
| 117 | CS MacLeod | Scotland v United States of America | Mannofield Park, Aberdeen | 2022 |
| 116* | IL Philip | Scotland v Ireland | The Village, Malahide, Dublin | 1991 |
| 116 | AC Storie | Scotland v England Amateur XI | Hamilton Crescent, Glasgow | 1994 |
| 116* | CS MacLeod | Scotland v Ireland | The Village, Malahide, Dublin | 2014 |
| 115 | TB Racionzer | Scotland v Ireland | The Meadow, Downpatrick | 1983 |
| 115* | JC Kent | Scotland v Sussex | County Ground, Hove | 2003 |
| 115 | GM Hamilton | Scotland v Canada | Sharjah Cricket Association Stadium, Sharjah | 2004/05 |
| 115 | GM Hamilton | Scotland v Ireland | Mannofield Park, Aberdeen | 2008 |
| 114 | BMW Patterson | Scotland v Ireland | Hamilton Crescent, Glasgow | 1994 |
| 114 | RS Dravid | Scotland v Northamptonshire | County Ground, Northampton | 2003 |
| 114 | MW Machan | Scotland v Kenya | Mannofield Park, Aberdeen | 2013 |
| 114 | MH Cross | Scotland v United Arab Emirates | Queens Sports Club, Bulawayo | 2017/18 |
| 114* | RD Berrington | Scotland v Papua New Guinea | Dubai Sports City Stadium, Dubai | 2022 |
| 113* | GF Goddard | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1973 |
| 113 | CS MacLeod | Scotland v United Arab Emirates | Queenstown Events Centre, Queenstown | 2013/14 |
| 112 | JS Carrick | Scotland v Nottinghamshire | Hamilton Crescent, Glasgow | 1889 |
| 112* | GN Reifer | Scotland v Earl of Arundel's XI | Arundel Castle Cricket Club Ground, Arundel | 1996 |
| 112 | KJ Coetzer | Scotland v Namibia | Raeburn Place, Edinburgh | 2017 |
| 111* | PL Mommsen | Scotland v United Arab Emirates | Raeburn Place, Edinburgh | 2016 |
| 110 | CT Mannes | Scotland v Gentlemen of Philadelphia | Raeburn Place, Edinburgh | 1889 |
| 110 | BR Hardie | Scotland v Marylebone Cricket Club | Mannofield Park, Aberdeen | 1971 |
| 110 | IL Philip | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1992 |
| 110 | IL Philip | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 110 | RD Berrington | Scotland v United Arab Emirates | Sharjah Cricket Association Stadium, Sharjah | 2011/12 |
| 110 | J Symes | Scotland v Durham | Emirates Durham International Cricket Ground, Chester-le-Street | 2012 |
| 110 | RD Berrington | Scotland v Namibia | Raeburn Place, Edinburgh | 2017 |
| 109 | AK McTavish | Scotland v South Americans | Raeburn Place, Edinburgh | 1932 |
| 109 | BMW Patterson | Scotland v Wales | Penrhyn Avenue, Rhos-on-Sea, Colwyn Bay | 2000 |
| 109 | NFI McCallum | Scotland v United Arab Emirates | Sharjah Cricket Association Stadium, Sharjah | 2006/07 |
| 109 | EF Chalmers | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2011 |
| 109 | KJ Coetzer | Scotland v Zimbabwe | Raeburn Place, Edinburgh | 2017 |
| 108 | J Aitchison | Scotland v Ireland | College Park, Dublin | 1951 |
| 108 | BR Hardie | Scotland v Marylebone Cricket Club | Mannofield Park, Aberdeen | 1971 |
| 108 | BMW Patterson | Scotland v Ireland | The Village, Malahide, Dublin | 1991 |
| 108* | RR Watson | Scotland v Derbyshire | County Ground, Derby | 2006 |
| 108 | MQ Sheikh | Scotland v Kenya | Gymkhana Club Ground, Nairobi | 2009/10 |
| 108* | KJ Coetzer | Scotland v United Arab Emirates | Choice Moosa Stadium, Pearland | 2022 |
| 107* | MH Cross | Scotland v United Arab Emirates | ICC Cricket Academy Ground, Dubai | 2017/18 |
| 107* | RD Berrington | Scotland v United States of America | Choice Moosa Stadium, Pearland | 2022 |
| 107* | MA Leask | Scotland v Nepal | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 107 | MM English | Scotland v Namibia | Forthill, Dundee | 2024 |
| 106* | J Aitchison | Scotland v South Africans | Whitehaugh Oval, Paisley | 1947 |
| 106 | AC Storie | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 106 | RD Berrington | Scotland v India A | Titwood, Glasgow | 2010 |
| 106 | EF Chalmers | Scotland v Kenya | Mannofield Park, Aberdeen | 2013 |
| 106* | MH Cross | Scotland v Sri Lanka | The Kent County Cricket Ground, Beckenham | 2017 |
| 106 | B McMullen | Scotland v Netherlands | Queens Sports Club, Bulawayo | 2023 |
| 106 | HG Munsey | Scotland v Netherlands | VRA Ground, Amstelveen | 2025 |
| 105 | RHE Chisholm | Scotland v Ireland | North Inch, Perth | 1970 |
| 105* | BMW Patterson | Scotland v Denmark | Boghall, Linlithgow | 1997 |
| 105 | RD Berrington | Scotland v Netherlands | Sportpark Maarschalkerweerd, Utrecht | 2025 |
| 104* | A Brown | Scotland v Warwickshire | Edgbaston, Birmingham | 1979 |
| 104* | NFI McCallum | Scotland v Afghanistan | Dubai Sports City Stadium, Dubai | 2010/11 |
| 104* | CS MacLeod | Scotland v Oman | Sharjah Cricket Association Stadium, Sharjah | 2011/12 |
| 103* | JA Fergusson | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1922 |
| 103* | H Wass | Scotland v Sir J Cahn's XI | West Park, West Bridgford | 1935 |
| 103 | J Aitchison | Scotland v Ireland | Whitehaugh Oval, Paisley | 1954 |
| 103 | JN Kemsley | Scotland v Marylebone Cricket Club | Mannofield Park, Aberdeen | 1957 |
| 103* | TB Racionzer | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1968 |
| 103 | AC Storie | Scotland v Marylebone Cricket Club | Lochside Park, Forfar | 1993 |
| 103* | GN Reifer | Scotland v Durham | Riverside Ground, Chester-le-Street | 1996 |
| 103* | RR Watson | Scotland v Somerset | Raeburn Place, Edinburgh | 2003 |
| 103 | NFI McCallum | Scotland v Namibia | LC de Villiers Oval, Pretoria | 2008/09 |
| 103 | CS MacLeod | Scotland v United Arab Emirates | Raeburn Place, Edinburgh | 2016 |
| 103* | HG Munsey | Scotland v Namibia | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 102 | TR Crosskey | Scotland v Warwickshire | Mannofield Park, Aberdeen | 1949 |
| 102 | J Aitchison | Scotland v Lancashire | Whitehaugh Oval, Paisley | 1956 |
| 102* | RS Weir | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1982 |
| 102* | O Henry | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 102* | IL Philip | Scotland v Somerset | County Ground, Taunton | 1992 |
| 102* | AC Storie | Scotland v Ireland | Hamilton Crescent, Glasgow | 1994 |
| 102 | R Flannigan | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 102 | PL Mommsen | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 102 | CS MacLeod | Scotland v Hong Kong | Raeburn Place, Edinburgh | 2016 |
| 102 | RD Berrington | Scotland v Nepal | Forthill, Dundee | 2025 |
| 101 | W Nicholson | Scotland v Ireland | College Park, Dublin | 1929 |
| 101 | GL Willatt | Scotland v New Zealanders | Hamilton Crescent, Glasgow | 1949 |
| 101* | NFI McCallum | Scotland v Uganda | Walter Milton Oval, University of Witwatersrand, Johannesburg | 2008/09 |
| 101 | DF Watts | Scotland v Canada | Mannofield Park, Aberdeen | 2009 |
| 101* | RD Berrington | Scotland v Ireland | The Village, Malahide, Dublin | 2014 |
| 101 | B McMullen | Scotland v Netherlands | Sportpark Maarschalkerweerd, Utrecht | 2025 |
| 100 | W Nichol | Scotland v Ireland | College Park, Dublin | 1951 |
| 100* | JN Kemsley | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1956 |
| 100 | J Aitchison | Scotland v Australians | Hamilton Crescent, Glasgow | 1956 |
| 100 | RG Swan | Scotland v Marylebone Cricket Club | North Inch, Perth | 1981 |
| 100 | BMW Patterson | Scotland v Ireland | Nunholm, Dumfries | 1988 |
| 100 | IL Philip | Scotland v Ireland | Myreside, Edinburgh | 1990 |
| 100* | MJ Smith | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1994 |
| 100 | NFI McCallum | Scotland v Ireland | Gymkhana Club Ground, Nairobi | 2006/07 |
| 100* | MQ Sheikh | Scotland v Ireland | Mannofield Park, Aberdeen | 2009 |
| 100 | RD Berrington | Scotland v Bangladesh | Sportpark Westvliet, Voorburg | 2012 |
| 100* | HG Munsey | Scotland v Namibia | Cambusdoon New Ground, Alloway | 2017 |
| 100 | CS MacLeod | Scotland v Afghanistan | Raeburn Place, Edinburgh | 2019 |