| 229* | DR Lockhart (119*) & GN Reifer (112*) | Scotland v Earl of Arundel's XI | Arundel Castle Cricket Club Ground, Arundel | 1996 |
| 188 | AC Storie (102*) & BMW Patterson (114) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1994 |
| 186 | HG Munsey (100*) & CS MacLeod (79) | Scotland v Namibia | Cambusdoon New Ground, Alloway | 2017 |
| 183 | OJ Hairs (127*) & B McMullen (96) | Scotland v Italy | Raeburn Place, Edinburgh | 2023 |
| 179 | CS MacLeod (116*) & HJW Gardiner (89) | Scotland v Ireland | The Village, Malahide, Dublin | 2014 |
| 177 | JR Laing (72) & TB Racionzer (125) | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1977 |
| 173 | DR Lockhart (151) & MQ Sheikh (92) | Scotland v Canada | Maple Leaf North-East Ground, King City | 2008 |
| 171 | RHE Chisholm (105) & JGB Laing (93) | Scotland v Ireland | North Inch, Perth | 1970 |
| 161 | MH Cross (114) & CS MacLeod (78) | Scotland v United Arab Emirates | Queens Sports Club, Bulawayo | 2017/18 |
| 154 | JG Williamson (89) & RA Parsons (75) | Scotland v South Africa Academy | Titwood, Glasgow | 1999 |
| 153 | LC Dudman (161) & J Aitchison (68) | Scotland v Warwickshire | Edgbaston, Birmingham | 1956 |
| 150 | Lord GW Scott (96) & JS Carrick (52) | Scotland v Yorkshire | Raeburn Place, Edinburgh | 1887 |
| 147* | K Scott (72*) & RG Swan (79*) | Scotland v Marylebone Cricket Club | Mannofield Park, Aberdeen | 1987 |
| 144 | CS MacLeod (175) & MW Machan (68) | Scotland v Canada | Hagley Oval, Christchurch | 2013/14 |
| 143 | LC Dudman (91) & RW Young (74) | Scotland v Warwickshire | Raeburn Place, Edinburgh | 1963 |
| 139 | RHE Chisholm (81) & J Aitchison (103) | Scotland v Ireland | Whitehaugh Oval, Paisley | 1954 |
| 139 | IL Philip (153*) & BMW Patterson (46) | Scotland v England Amateur XI | Osborne Avenue, Jesmond | 1991 |
| 135 | BMW Patterson (77) & MJ Smith (73) | Scotland v Gloucestershire | The Royal and Sun Alliance County Ground, Bristol | 1997 |
| 134 | KJ Coetzer (133) & JH Davey (64) | Scotland v Afghanistan | Sharjah Cricket Association Stadium, Sharjah | 2012/13 |
| 133 | WA Donald (92) & RG Swan (53) | Scotland v Worcestershire | Forthill, Dundee | 1982 |
| 130 | KJ Coetzer (64) & DF Watts (73) | Scotland v Uganda | Gymkhana Club Ground, Nairobi | 2009/10 |
| 126 | TB Racionzer (55) & DL Bell (63) | Scotland v Marylebone Cricket Club | Mannofield Park, Aberdeen | 1979 |
| 125 | MH Cross (74*) & B McMullen (69) | Scotland v West Indies | Harare Sports Club, Harare | 2023 |
| 124 | DBS Brown (132) & TB Racionzer (55) | Scotland v Wales | Forthill, Dundee | 1976 |
| 123 | DF Watts (88) & IM Stanger (65) | Scotland v Warwickshire | Raeburn Place, Edinburgh | 2005 |
| 121 | CJ Warner (55) & RG Swan (66) | Scotland v Ireland | Myreside, Edinburgh | 1982 |
| 121 | GM Hamilton (127) & NFI McCallum (54) | Scotland v United Arab Emirates | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 120 | DF Watts (55) & RR Watson (94) | Scotland v Ireland | Castle Avenue, Dublin | 2005 |
| 120 | HG Munsey (91) & B McMullen (37) | Scotland v Namibia | Forthill, Dundee | 2024 |
| 119 | DBS Brown (29) & TB Racionzer (124) | Scotland v Warwickshire | Edgbaston, Birmingham | 1976 |
| 119 | IM Stanger (40) & RR Watson (108*) | Scotland v Derbyshire | County Ground, Derby | 2006 |
| 118 | A Steele (74) & AM Zuill (62) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1968 |
| 118 | BMW Patterson (71) & MJD Allingham (54) | Scotland v Worcestershire | Raeburn Place, Edinburgh | 1998 |
| 118 | RO Hussain (42) & GJ Bailey (90) | Scotland v Hampshire | The Rose Bowl, Southampton | 2010 |
| 115 | BMW Patterson (51) & DF Watts (79) | Scotland v Netherlands | Mannofield Park, Aberdeen | 2004 |
| 114 | DR Lockhart (64) & CJO Smith (68*) | Scotland v Ireland | Malton Cricket Club, Toronto | 2001 |
| 111 | DF Watts (54) & MQ Sheikh (63) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2007/08 |
| 109 | IL Philip (102*) & GN Reifer (55) | Scotland v Somerset | County Ground, Taunton | 1992 |
| 109 | BG Lockie (54) & DR Lockhart (75) | Scotland v Durham | Riverside Ground, Chester-le-Street | 1998 |
| 106 | KJ Coetzer (83) & CS MacLeod (57) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2017 |
| 105 | JR Laing (34) & BR Hardie (110) | Scotland v Marylebone Cricket Club | Mannofield Park, Aberdeen | 1971 |
| 105 | R Flannigan (60) & RM Haq (120*) | Scotland v Netherlands | Mannofield Park, Aberdeen | 2011 |
| 104 | CJ Tear (51) & B McMullen (151) | Scotland v United States of America | Grand Prairie Stadium, Grand Prairie | 2024/25 |
| 103 | IL Philip (83) & AC Storie (37) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1990 |
| 103 | BG Lockie (74) & DR Lockhart (39) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1996 |
| 103 | NJ MacRae (51) & MJD Allingham (66*) | Scotland v South Africa Academy | Forthill, Dundee | 1999 |
| 102* | J Kerr (62*) & J Greive (55*) | Scotland v Ireland | Raeburn Place, Edinburgh | 1920 |
| 102 | RM Haq (59) & PL Mommsen (102) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |