| 301 | IL Philip (234) & AC Storie (106) | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 236 | IL Philip (116*) & BMW Patterson (108) | Scotland v Ireland | The Village, Malahide, Dublin | 1991 |
| 215 | BMW Patterson (98) & IL Philip (110) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1992 |
| 203 | J Kerr (137) & IT Parker (62) | Scotland v Ireland | Glenpark, Greenock | 1926 |
| 203 | GM Hamilton (119) & DF Watts (101) | Scotland v Canada | Mannofield Park, Aberdeen | 2009 |
| 201 | MH Cross (106*) & KJ Coetzer (118) | Scotland v Sri Lanka | The Kent County Cricket Ground, Beckenham | 2017 |
| 200 | HG Munsey (127*) & KJ Coetzer (89) | Scotland v Netherlands | The Village, Malahide, Dublin | 2019 |
| 198 | IL Philip (121) & BG Lockie (70) | Scotland v Ireland | Main Road, Ynysygerwn | 1996 |
| 189 | GL Willatt (144*) & TR Crosskey (102) | Scotland v Warwickshire | Mannofield Park, Aberdeen | 1949 |
| 185 | AC Storie (103) & GN Reifer (74) | Scotland v Marylebone Cricket Club | Lochside Park, Forfar | 1993 |
| 179* | DF Watts (75*) & NJ MacRae (88*) | Scotland v Italy | Hamilton Crescent, Glasgow | 2006 |
| 178 | MH Cross (88) & CS MacLeod (113) | Scotland v United Arab Emirates | Queenstown Events Centre, Queenstown | 2013/14 |
| 169 | GL Willatt (101) & TR Crosskey (81) | Scotland v New Zealanders | Hamilton Crescent, Glasgow | 1949 |
| 157* | KJ Coetzer (46*) & HG Munsey (103*) | Scotland v Namibia | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 156 | BMW Patterson (64) & IL Philip (121*) | Scotland v England Amateur XI | Raeburn Place, Edinburgh | 1992 |
| 150 | J Kerr (88) & GWA Alexander (136) | Scotland v Ireland | Mannofield Park, Aberdeen | 1930 |
| 148 | JS Carrick (112) & TR Marshall (51) | Scotland v Nottinghamshire | Hamilton Crescent, Glasgow | 1889 |
| 147 | IL Philip (100) & BMW Patterson (60) | Scotland v Ireland | Myreside, Edinburgh | 1990 |
| 145* | CJ Tear (43*) & ARI Umeed (98*) | Scotland v United States of America | Grand Prairie Stadium, Grand Prairie | 2024/25 |
| 144 | BMW Patterson (63) & IL Philip (80) | Scotland v Lancashire | Old Trafford, Manchester | 1992 |
| 141 | DF Watts (98) & PL Mommsen (80) | Scotland v Ireland | VRA Ground, Amstelveen | 2010 |
| 138 | MH Cross (53) & KJ Coetzer (95) | Scotland v United Arab Emirates | ICC Cricket Academy Ground, Dubai | 2019/20 |
| 133 | RHE Chisholm (57) & A Steele (97) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1968 |
| 129 | DF Watts (54) & KJ Coetzer (89) | Scotland v Ireland | Raeburn Place, Edinburgh | 2011 |
| 127 | IL Philip (71) & BG Lockie (58) | Scotland v Italy | University of Malaya, Kuala Lumpur | 1996/97 |
| 123 | J Kerr (136) & AJ Stevenson (45) | Scotland v Ireland | College Park, Dublin | 1927 |
| 118 | RHE Chisholm (54) & JM Allan (65) | Scotland v Warwickshire | Courtaulds Ground, Coventry | 1954 |
| 115 | J Kerr (75) & AW Angus (29) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1922 |
| 115* | DR Lockhart (47*) & CM Wright (58*) | Scotland v Singapore | Malton Cricket Club, Toronto | 2001 |
| 112 | RD Berrington (52) & CS MacLeod (56) | Scotland v Italy | Sheikh Zayed Stadium Nursery 2, Abu Dhabi | 2013/14 |
| 111 | LM Balfour-Melville (91) & J Anderson (31) | Scotland v Ireland | North Inch, Perth | 1909 |
| 111 | TB Racionzer (125) & SK Dharsi (48) | Scotland v Netherlands | Hamilton Crescent, Glasgow | 1980 |
| 111 | BMW Patterson (55) & IL Philip (79) | Scotland v Ireland | Forthill, Dundee | 1992 |
| 111 | BMW Patterson (61) & IL Philip (102*) | Scotland v Somerset | County Ground, Taunton | 1992 |
| 109 | DR Lockhart (49) & GI Maiden (51) | Scotland v England and Wales Cricket Board XI | Sportpark Maarschalkerweerd, Utrecht | 2004 |
| 109 | HG Munsey (50) & KJ Coetzer (74) | Scotland v Ireland | Al Amerat Cricket Ground, Al Amerat | 2018/19 |
| 108 | J Kerr (59) & JF Jones (78) | Scotland v Ireland | Glenpark, Greenock | 1932 |
| 108 | BG Lockie (54) & ST Crawley (55) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1998 |
| 108* | JH Davey (44*) & CS MacLeod (58*) | Scotland v Nottinghamshire | Raeburn Place, Edinburgh | 2012 |
| 107 | BMW Patterson (37) & IL Philip (83) | Scotland v England Amateur XI | Myreside, Edinburgh | 1992 |
| 104 | IL Philip (55) & AC Storie (116) | Scotland v England Amateur XI | Hamilton Crescent, Glasgow | 1994 |
| 104 | RD Berrington (30) & CS MacLeod (104*) | Scotland v Oman | Sharjah Cricket Association Stadium, Sharjah | 2011/12 |
| 103* | BMW Patterson (40*) & DG Wright (53*) | Scotland v Dorset | Boghall, Linlithgow | 2001 |
| 103 | DF Watts (58) & RM Haq (71) | Scotland v Kenya | Gymkhana Club Ground, Nairobi | 2006/07 |
| 103 | MH Cross (48) & KJ Coetzer (58) | Scotland v England | Raeburn Place, Edinburgh | 2018 |
| 102 | RR Watson (54) & KJ Coetzer (48*) | Scotland v Kenya | Civil Service Cricket Club, Stormont, Belfast | 2008 |
| 100 | RD Berrington (43) & CS MacLeod (58) | Scotland v Papua New Guinea | ICC Cricket Academy Ground, Dubai | 2013/14 |