| 176 | JD Henderson (83) & WA Edward (99) | Scotland v Ireland | North Inch, Perth | 1950 |
| 150 | TB Racionzer (103*) & J Brown (70) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1968 |
| 141* | JR Laing (127*) & KM Hardie (65*) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1976 |
| 125 | RO Hussain (52) & CM Wright (88*) | Scotland v Surrey | The Brit Oval, Kennington | 2005 |
| 122 | KJ Coetzer (133*) & CM Wright (59) | Scotland v Kenya | Sheikh Zayed Stadium, Abu Dhabi | 2004/05 |
| 116 | W Nichol (83) & WK Laidlaw (36) | Scotland v Durham | Ashbrooke, Sunderland | 1949 |
| 113 | D Barr (52*) & J Brown (69) | Scotland v Lancashire | Old Trafford, Manchester | 1967 |
| 109 | JGB Laing (93) & D Barr (49) | Scotland v Warwickshire | Edgbaston, Birmingham | 1965 |
| 106 | RH Johnston (89) & AR Don Wauchope (51) | Scotland v Gloucestershire | Raeburn Place, Edinburgh | 1891 |
| 104 | NFI McCallum (100) & CJO Smith (49*) | Scotland v Ireland | Gymkhana Club Ground, Nairobi | 2006/07 |
| 99 | RD Berrington (62) & JH Davey (53*) | Scotland v Afghanistan | Sheikh Zayed Stadium, Abu Dhabi | 2014/15 |
| 95 | FA Jones (77) & J Brown (47) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1960 |
| 93 | H Wass (103*) & HL Stewart (29) | Scotland v Sir J Cahn's XI | West Park, West Bridgford | 1935 |
| 92 | AR Don Wauchope (36) & CT Mannes (110) | Scotland v Gentlemen of Philadelphia | Raeburn Place, Edinburgh | 1889 |
| 91 | A Brown (74) & PG Duthie (54*) | Scotland v Ireland | Titwood, Glasgow | 1986 |
| 91 | FDW McCreath (81) & MRJ Watt (60) | Scotland v Netherlands | Forthill, Dundee | 2025 |
| 88 | W Webster (65) & WH Thorburn (90*) | Scotland v Ireland | North Inch, Perth | 1909 |
| 85 | WE Benskin (79*) & JH Orr (29) | Scotland v Australians | North Inch, Perth | 1912 |
| 81 | MA Leask (107*) & JA Jarvis (26) | Scotland v Nepal | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 80 | BL Peel (74) & HD Keigwin (36) | Scotland v South Africans | Raeburn Place, Edinburgh | 1907 |
| 79 | DH Dewar (72) & WK Laidlaw (37) | Scotland v Sir J Cahn's XI | West Park, West Bridgford | 1939 |
| 79 | CJ Warner (48) & DG Moir (44) | Scotland v Ireland | Langloan, Coatbridge | 1980 |
| 77 | RR Watson (86) & CM Wright (13) | Scotland v Durham | Riverside Ground, Chester-le-Street | 2005 |
| 77 | PL Mommsen (73*) & RM Haq (30) | Scotland v Durham | Emirates Durham International Cricket Ground, Chester-le-Street | 2011 |
| 76 | [unknown] & [unknown] | Scotland v Ireland | Glenpark, Greenock | 1926 |
| 72 | IM Stanger (54) & MA Mudie (25*) | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1997 |
| 70 | RS Weir (89) & GF Goddard (16*) | Scotland v Pakistan International Airlines | Titwood, Glasgow | 1976 |
| 68 | CM Wright (40) & JD Nel (25) | Scotland v Namibia | Mannofield Park, Aberdeen | 2006 |
| 65 | R Ellis (69) & J Brown (15) | Scotland v Warwickshire | Edgbaston, Birmingham | 1971 |
| 65 | A Brown (21) & AB Russell (73*) | Scotland v Nottinghamshire | Titwood, Glasgow | 1985 |
| 63 | J Brown (90) & WDF Dow (15) | Scotland v Yorkshire | Whitehaugh Oval, Paisley | 1957 |
| 63 | MA Leask (85) & MRJ Watt (31) | Scotland v New Zealand | Raeburn Place, Edinburgh | 2022 |
| 62 | CT Mannes (55) & DA Steele (18) | Scotland v Gloucestershire | Raeburn Place, Edinburgh | 1893 |
| 62 | HL Stewart (65*) & J Greive (38) | Scotland v Sir J Cahn's XI | Stanford Hall, Stanford | 1935 |
| 62 | J Aitchison (37) & A Johnston (50*) | Scotland v Yorkshire | North Marine Road, Scarborough | 1951 |
| 61 | GM Hamilton (76) & AG Davies (19) | Scotland v Pakistan | Riverside Ground, Chester-le-Street | 1999 |
| 61* | MA Leask (51*) & MRJ Watt (13*) | Scotland v Papua New Guinea | Al Amerat Cricket Ground, Al Amerat | 2021 |
| 61 | MH Cross (85) & MRJ Watt (29) | Scotland v United Arab Emirates | Mannofield Park, Aberdeen | 2022 |
| 61* | CN Greaves (30*) & MRJ Watt (31*) | Scotland v Jersey | Raeburn Place, Edinburgh | 2023 |
| 61 | MH Cross (43*) & MRJ Watt (28) | Scotland v Jersey | Sportpark Westvliet, Voorburg | 2025 |
| 60 | JMC Ford (66*) & JM Allan (12) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1962 |