| 202 | R Flannigan (115*) & RD Berrington (111) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2010 |
| 177 | MM English (110) & DE Budge (109) | Scotland A v Bath | North Parade, Bath | 2018 |
| 173 | CJO Smith (97) & NFI McCallum (93) | Scotland v Pretoria University | LC de Villiers Oval, Pretoria | 2008/09 |
| 168 | BMW Patterson (125) & G Salmond (52) | Scotland B v Nottinghamshire Second XI | Trent Bridge, Nottingham | 1990 |
| 153* | RD Berrington (87*) & HG Munsey (73*) | Scotland v Netherlands | Groenkloof Oval, Pretoria | 2017/18 |
| 151 | MA Leask (111) & DE Budge (55) | Scotland A v Gloucestershire Second XI | North Parade, Bath | 2018 |
| 138 | PL Mommsen (63) & HG Munsey (86) | Scotland A v Lancashire Second XI | Parkgate, Neston | 2018 |
| 137* | SR Kennedy (70*) & MJD Allingham (59*) | Scotland B v Star Club of India | Titwood, Glasgow | 1993 |
| 135 | NFI McCallum (97) & RO Hussain (76) | Scotland A v Durham Second XI | Raeburn Place, Edinburgh | 2006 |
| 123 | G Salmond (117) & DAJ Rigby (56) | Scotland B v Durham Second XI | Denton Bank, Benwell Hill | 1993 |
| 123 | FRJ Coleman (64) & PL Mommsen (70*) | Scotland v Essex | Raeburn Place, Edinburgh | 2013 |
| 121 | GBJ McGurk (64) & MJ Smith (61) | Scotland v Netherlands A | Sportpark Bergenshuizen, Vught | 1994 |
| 114 | NJ MacRae (55) & MQ Sheikh (104) | Scotland A v Yorkshire Second XI | Abbeydale Park, Sheffield | 2008 |
| 114 | PL Mommsen (105) & RD Berrington (43) | Scotland XI v United Arab Emirates | The Ageas Bowl, Southampton | 2015 |
| 111 | HJW Gardiner (54) & MW Machan (83) | Scotland v New Zealand XI | Bert Sutcliffe Oval, Lincoln | 2014/15 |
| 110 | KJ Coetzer (128) & RD Berrington (54) | Scotland v Otago | Bert Sutcliffe Oval, Lincoln | 2014/15 |
| 105 | CV English (51) & CJO Smith (61) | Scotland v Ireland | Pollock Park, Lurgan | 2005 |
| 96 | IM Stanger (52) & MQ Sheikh (42) | Scotland A v Ireland A | Cambusdoon New Ground, Alloway | 2006 |
| 96 | MW Machan (103) & PL Mommsen (56) | Scotland v Ireland | Blacktown Olympic Park Oval, Sydney | 2014/15 |
| 94 | DE Budge (105) & RD Berrington (93) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2015 |
| 94* | MH Cross (101*) & CD Wallace (32*) | Scotland v Papua New Guinea | Bulawayo Athletic Club, Bulawayo | 2017/18 |
| 93 | RA Parsons (37) & CJO Smith (155*) | Scotland B v Durham University Second XI | The Racecourse, Durham | 1999 |
| 91 | CV English (107) & DR Lockhart (22) | Scotland XI v Glamorgan | Sophia Gardens, Cardiff | 2002 |
| 91 | RD Berrington (126) & CS MacLeod (18) | Scotland A v Northamptonshire Second XI | West Lodge Park, Desborough | 2012 |
| 90 | PL Mommsen (55) & DE Budge (52) | Scotland A v Lancashire Second XI | Parkgate, Neston | 2018 |
| 89 | RD Berrington (145) & HG Munsey (33) | Scotland v Auckland | Kerrydale, Robina | 2017/18 |
| 88 | BG Lockie (100*) & CJO Smith (43) | Scotland B v Yorkshire Second XI | Park Avenue Cricket Ground, Bradford | 1997 |
| 88 | DF Watts (72) & KA McLaren (84) | Scotland A v Ireland A | Instonians Cricket Club, Shaw's Bridge Lower Ground, Belfast | 2003 |
| 88 | MQ Sheikh (95) & RD Berrington (41) | Scotland A v Yorkshire Second XI | The Playing Field, Stamford Bridge | 2007 |
| 85 | PL Mommsen (55) & KJ Coetzer (83) | Scotland v Canterbury | Hagley Oval, Christchurch | 2014/15 |
| 82 | RG Swan (78) & O Henry (82*) | Scotland XI v Worcestershire | County Ground, New Road, Worcester | 1984 |
| 82 | HJW Gardiner (73) & JR Edwards (33) | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 79 | RA Parsons (117) & IL Philip (35) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1995 |
| 79 | MQ Sheikh (73) & RO Hussain (124*) | Scotland A v Lancashire Second XI | Meikleriggs, Paisley | 2006 |
| 79 | T Booth (67*) & BD Birkhead (38) | Yorkshire Academy v Scotland Development XI | Weetwood Playing Fields, Leeds | 2013 |
| 78 | EF Chalmers (59) & MM Iqbal (36) | Scotland A v Netherlands A | Les Quennevais, St Brelade | 2010 |
| 78 | R Flannigan (28) & RD Berrington (82) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2010 |
| 77 | RG Swan (53) & ETN Pollock (58) | Scotland B v Central Lancashire League | Nunholm, Dumfries | 1981 |
| 77 | MJ Smith (70) & GN Reifer (30) | Scotland v Glostrup | Solvangs Park, Glostrup | 1996 |
| 75 | SD Gilmour (44) & NFI McCallum (101*) | Scotland B v Durham University | The Racecourse, Durham | 2000 |
| 74 | HK More (88) & DER Stewart (36) | Scotland v Ireland | Titwood, Glasgow | 1976 |
| 74 | RA Parsons (35) & G Salmond (41*) | Scotland XI v Durham Second XI | Eastwood Gardens, Gateshead | 2001 |
| 74 | RD Berrington (28) & RO Hussain (47) | Scotland A v Yorkshire Second XI | Weetwood Playing Fields, Leeds | 2009 |
| 74 | RA Johnston (27) & MM English (108) | Scotland A v Northamptonshire Second XI | Campbell Park, Milton Keynes | 2018 |
| 73 | J Everett (27) & RC Smith (59) | Scotland B v Star Club of India | The Tryst, Stenhousemuir | 1991 |
| 73 | RR Watson (30) & DR Brown (54*) | Scotland XI v Barbados | Three Ws Oval, Cave Hill | 2005/06 |
| 72 | J Everett (29) & G Salmond (89) | Scotland XI v Northern Transvaal League | Berea Park, Pretoria | 1991/92 |
| 72 | AC Storie (142) & RA Parsons (32*) | Scotland B v Durham University | The Racecourse, Durham | 1996 |