| 187 | JD Henderson (121) & WA Edward (73) | Scotland v Ireland | Whitehaugh Oval, Paisley | 1954 |
| 174 | RD Berrington (106) & MM Iqbal (67) | Scotland v India A | Titwood, Glasgow | 2010 |
| 126* | CM Wright (45*) & GI Maiden (79*) | Scotland v Ireland | East Grinstead Sports Club Ground, East Grinstead | 2001 |
| 125 | KM Hardie (41) & GF Goddard (113*) | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1973 |
| 110 | RD Berrington (127) & MRJ Watt (44*) | Scotland v United Arab Emirates | Bulawayo Athletic Club, Bulawayo | 2023 |
| 94 | JM Allan (55*) & J Brown (46) | Scotland v Warwickshire | Edgbaston, Birmingham | 1966 |
| 90 | [unknown] & [unknown] | Scotland v Surrey Club | Kennington Oval, Kennington | 1865 |
| 90 | CM Wright (43) & RM Haq (55*) | Scotland v Durham | Raeburn Place, Edinburgh | 2003 |
| 89 | A Blacklock (48) & AS Cairns (56) | Scotland v GL Jessop's XI | Raeburn Place, Edinburgh | 1903 |
| 84 | J Aitchison (91) & JD Henderson (42) | Scotland v Sussex | County Ground, Hove | 1950 |
| 83* | CN Greaves (53*) & SM Sharif (40*) | Scotland v Namibia | Titwood, Glasgow | 2022 |
| 82 | MA Leask (91*) & MRJ Watt (47) | Scotland v Ireland | Queens Sports Club, Bulawayo | 2023 |
| 80 | PL Mommsen (68*) & SM Sharif (26) | Scotland v Netherlands | Raeburn Place, Edinburgh | 2015 |
| 79 | JAR Blain (93) & SJS Smith (40) | Scotland v Ireland | Civil Service Cricket Club, Stormont, Belfast | 2007 |
| 79 | RM Haq (37) & SM Sharif (60) | Scotland v Ireland | Castle Avenue, Dublin | 2013 |
| 77 | F Robertson (67) & JE Ker (45) | Scotland v Lancashire | Old Trafford Practice Ground, Manchester | 1978 |
| 76 | GJ Bailey (92) & JAR Blain (22*) | Scotland v Durham | Riverside Ground, Chester-le-Street | 2007 |
| 76 | MA Leask (107*) & MRJ Watt (20) | Scotland v Nepal | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 69 | JH Stander (64) & GD Drummond (34) | Scotland v Canada | Mannofield Park, Aberdeen | 2009 |
| 67 | RS Hodge (78) & SJ Thomson (14) | Scotland v Marylebone Cricket Club | Raeburn Place, Edinburgh | 1939 |
| 67 | GF Goddard (29) & JE Ker (50) | Scotland v New Zealanders | Forthill, Dundee | 1978 |
| 65 | MA Parker (65) & RM Haq (30) | Scotland v Netherlands | Sportpark Het Schootsveld, Deventer | 2010 |
| 64 | CT Mannes (110) & AS Caldwell (7) | Scotland v Gentlemen of Philadelphia | Raeburn Place, Edinburgh | 1889 |
| 64 | MJ Smith (79) & JE Ker (26*) | Scotland v Ireland | Lodge Road, Coleraine | 1987 |
| 63 | RM Haq (55) & D Murphy (26) | Scotland v New Zealand A | Raeburn Place, Edinburgh | 2014 |
| 62 | W Nichol (139*) & RS Hodge (27) | Scotland v Warwickshire | Edgbaston, Birmingham | 1951 |
| 62 | CS MacLeod (133*) & SM Sharif (25) | Scotland v United States of America | Mannofield Park, Aberdeen | 2022 |
| 61 | RD Berrington (129) & MRJ Watt (81*) | Scotland v Papua New Guinea | Amini Park, Port Moresby | 2017/18 |
| 59 | GF Goddard (82*) & ER Thompson (29) | Scotland v Marylebone Cricket Club | Myreside, Edinburgh | 1975 |
| 59* | FRJ Coleman (64*) & SM Sharif (25*) | Scotland v Nepal | Queenstown Events Centre, Queenstown | 2013/14 |
| 58 | RD Berrington (80) & RT Lyons (23) | Scotland v Kenya | Gymkhana Club Ground, Nairobi | 2009/10 |
| 57 | DF Watts (98) & GD Drummond (30) | Scotland v Ireland | VRA Ground, Amstelveen | 2010 |
| 56 | PG Duthie (34) & JE Ker (20*) | Scotland v Ireland | Titwood, Glasgow | 1984 |
| 56* | NFI McCallum (121*) & JH Stander (22*) | Scotland v Ireland | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 56 | MM Iqbal (25) & SM Sharif (41) | Scotland v Ireland | Castle Avenue, Dublin | 2013 |
| 54 | JM Allan (99*) & J Brown (35) | Scotland v New Zealanders | Hamilton Crescent, Glasgow | 1965 |
| 54 | MA Leask (50) & SM Sharif (18) | Scotland v Ireland | The Village, Malahide, Dublin | 2014 |
| 53 | GF Goddard (39) & J Brown (48*) | Scotland v Ireland | Whitehaugh Oval, Paisley | 1960 |
| 53 | MA Mudie (18) & K Thomson (37) | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1997 |
| 52 | O Henry (58*) & JW Govan (16) | Scotland v Lancashire | North Inch, Perth | 1989 |
| 52 | IA Moran (34) & JAR Blain (19*) | Scotland v Derbyshire | Raeburn Place, Edinburgh | 2007 |
| 52 | MM Iqbal (63) & GD Drummond (33*) | Scotland v Netherlands | VRA Ground, Amstelveen | 2010 |
| 51 | W Nichol (56) & RS Hodge (24) | Scotland v Ireland | Glenpark, Greenock | 1946 |
| 51 | D Barr (23) & ER Thompson (33) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1970 |
| 50 | CD Wallace (46) & AC Evans (22) | Scotland v Sri Lanka | The Kent County Cricket Ground, Beckenham | 2017 |