| 154 | SM Sharif (106*) & JW Dickinson (59) | Scotland A v Northamptonshire Second XI | Campbell Park, Milton Keynes | 2018 |
| 92 | MA Leask (48) & G Goudie (46*) | Scotland A v Derbyshire Second XI | The Copper Yard, Denby Village | 2012 |
| 77 | GI Maiden (69*) & GD Drummond (26) | Scotland XI v United Arab Emirates | Dubai Sports City Stadium, Dubai | 2010/11 |
| 75* | MA Leask (92*) & MRJ Watt (32*) | Scotland v United Arab Emirates Falcons | Dubai Sports City Stadium, Dubai | 2023/24 |
| 72 | MA Parker (74) & G Goudie (47*) | Scotland A v Leicestershire Second XI | Bath Grounds, Ashby-de-la-Zouch | 2010 |
| 72* | MH Cross (54*) & CG Burnett (31*) | Scotland v Essex | The Essex County Ground, Chelmsford | 2013 |
| 69 | SW Currie (45) & MRJ Watt (45*) | Scotland v United Arab Emirates Falcons | Dubai Sports City Stadium, Dubai | 2023/24 |
| 67 | JH Stander (97) & UA Mohammad (38) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2007 |
| 59 | [unknown] & [unknown] | Scotland XI v Barbados | Three Ws Oval, Cave Hill | 2005/06 |
| 56* | G Salmond (120*) & RJ Mitchinson (12*) | Scotland B v Yorkshire Second XI | Park Avenue Cricket Ground, Bradford | 1997 |
| 56 | AJL Baum (38*) & GT Main (15) | Scotland Development XI v Northamptonshire Second XI | County Ground, Northampton | 2013 |
| 54 | CG Burnett (36*) & A Bailwal (29) | Scotland A v Ireland A | Bothwell Castle, Uddingston | 2012 |
| 54 | SM Sharif (48*) & MRJ Watt (17) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2015 |
| 53 | G Goudie (30*) & Z Bashir (36) | Scotland A v Derbyshire Second XI | Christchurch Meadows, Belper | 2008 |
| 53 | DE Budge (116*) & MH Waugh (15) | Scotland Development XI v Yorkshire Academy | Weetwood Playing Fields, Leeds | 2015 |
| 52* | DA Orr (66*) & K Thomson (14*) | Scotland B v Durham University | The Racecourse, Durham | 1992 |
| 52 | H Aslam (52*) & GT Main (30) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2016 |
| 49 | MA Leask (36) & SM Sharif (19*) | Scotland A v Northamptonshire Second XI | Campbell Park, Milton Keynes | 2018 |
| 48 | WDG Loudon (62) & JE Ker (6) | Scotland XI v Worcestershire | County Ground, New Road, Worcester | 1982 |
| 48 | FRJ Coleman (28*) & RM Haq (21) | Scotland v Tasmania | Kingston Twin Ovals, Hobart | 2014/15 |
| 45* | JAR Blain (31*) & RR Watson (20*) | Scotland v Tanzania | Sir Ali Muslim Club Ground, Nairobi | 2006/07 |
| 44 | AHJ Hislop (38) & RT Lyons (21) | Scotland Under-23s v Cavaliers | Hamilton Crescent, Glasgow | 2006 |
| 41 | SD Weeraratna (24) & RT Lyons (12*) | Scotland Under-23s v Ireland Under-23s | The Vineyard, Dublin | 2006 |
| 41 | JD Nel (43) & RT Lyons (28*) | Scotland v Barbados XI | Three Ws Oval, Cave Hill | 2006/07 |
| 40 | MQ Sheikh (95) & RT Lyons (18*) | Scotland A v Yorkshire Second XI | The Playing Field, Stamford Bridge | 2007 |
| 40* | SM Sharif (18*) & D Murphy (24*) | Scotland v Sri Lanka Ports Authority Cricket Club | Nondescripts Cricket Club Ground, Colombo | 2013/14 |
| 39* | MH Cross (39*) & G Goudie (9*) | Scotland v Namibia | Christ's College, Christchurch | 2013/14 |
| 39 | J Cook (20) & A Walsh (28*) | St George v Scotland | Hurstville Oval, Sydney | 2014/15 |
| 38 | EF Chalmers (55*) & WJ Rowan (21) | Scotland A v Nottinghamshire Second XI | Sports Ground, Cleethorpes | 2009 |
| 36 | SJS Smith (61*) & G Goudie (9) | Scotland A v Derbyshire Second XI | Christchurch Meadows, Belper | 2008 |
| 36 | AC Evans (21*) & MD Rao (9) | Scotland A v Gloucestershire Second XI | North Parade, Bath | 2017 |
| 35* | JW Govan (27*) & D Cowan (19*) | Scotland XI v Rand Afrikaans University | Eben Cuyler Park, Johannesburg | 1991/92 |
| 34* | JAR Blain (33*) & RJ Mitchinson (4*) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1996 |
| 34 | SJ Chalmers (18) & RT Lyons (18*) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2009 |
| 34 | MRJ Watt (57*) & GT Main (6) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2016 |
| 32 | MM Iqbal (29) & MRJ Watt (10) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2014 |
| 31 | MRJ Watt (13) & PT Sadler (21*) | Scotland Development XI v Yorkshire Academy | Weetwood Playing Fields, Leeds | 2013 |
| 31* | MH Cross (64*) & MA Leask (10*) | Scotland v Tasmania | Anzac Park, Hobart | 2014/15 |
| 30 | RO Hussain (121) & NJ MacRae (27*) | Scotland A v Yorkshire Second XI | The Playing Field, Stamford Bridge | 2007 |
| 30 | MRJ Watt (68) & MD Rao (20) | Scotland A v Ireland Wolves | Claremont Road, Dublin | 2017 |
| 29* | DM Peden (42*) & F Robertson (15*) | Scotland v Ireland | Titwood, Glasgow | 1976 |
| 29* | GI Maiden (19*) & JAR Blain (14*) | Scotland v Ireland | Pollock Park, Lurgan | 2005 |
| 29 | RM Haq (68*) & G Goudie (23) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2013 |
| 28 | [unknown] & [unknown] | Ireland XI v Scotland XI | Observatory Lane, Rathmines, Dublin | 1888 |
| 28 | SJS Smith (14) & SD Weeraratna (12) | Scotland A v Nottinghamshire Second XI | Caythorpe Road, Caythorpe | 2007 |
| 27 | JG Williamson (81) & A Agrawalla (11*) | Scotland B v Star Club of India | Titwood, Glasgow | 1994 |
| 27 | GI Maiden (22*) & JE Brinkley (9) | Scotland v Papua New Guinea | Kaiteur Cricket Club, Kitchener | 2001 |
| 27 | SP Patil (100) & Mohammad Tauqir (6) | United Arab Emirates v Scotland XI | The Ageas Bowl, Southampton | 2015 |
| 26 | WJ Reid (13) & R Scott (20*) | Scotland XI v England XI | Hamilton Crescent, Glasgow | 1891 |
| 26 | HC Barbour (17) & GJ Luyt (9) | Scotland XI v South Africans | Hamilton Crescent, Glasgow | 1907 |
| 26 | [unknown] & [unknown] | Scotland XI v Ireland XI | Mannofield Park, Aberdeen | 1930 |
| 25 | PG Duthie (63) & JR Goodall (2*) | Scotland B v Leicestershire Second XI | Coventry Road, Lutterworth | 1984 |
| 25 | AJL Baum (53*) & NS Alexander (2) | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 25 | CD Wallace (35) & CG Burnett (15) | Scotland v Surrey | The Kia Oval, Kennington | 2013 |
| 25 | MM Iqbal (21) & I Wardlaw (9) | Scotland A v Durham Second XI | The Racecourse, Durham | 2014 |