| 109* | RM Haq (68*) & CG Burnett (61*) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2013 |
| 79* | ST Knox (66*) & RT Routray (14*) | Scotland B v Marylebone Cricket Club | Denis Compton Oval, Shenley | 2004 |
| 73 | SD Weeraratna (70*) & Z Bashir (32) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2008 |
| 66 | A Bailwal (24*) & G Goudie (38) | Scotland A v Ireland A | Bothwell Castle, Uddingston | 2012 |
| 63 | G Goudie (47*) & RT Lyons (35) | Scotland A v Leicestershire Second XI | Bath Grounds, Ashby-de-la-Zouch | 2010 |
| 53 | MJ Petrie (35*) & CG Burnett (29) | Scotland A v England Under-18s | Titwood, Glasgow | 2009 |
| 49 | MA Leask (50*) & G Goudie (15) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2011 |
| 48* | Z Bashir (32*) & TJ Buchan (10*) | Scotland A v Jersey | Farmers Cricket Club Ground, St Martin | 2010 |
| 43 | MD Rao (34*) & A Neill (8) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2016 |
| 41 | SJ Cameron (59*) & CJ Shoebridge (3) | Scotland A v Ireland Wolves | Claremont Road, Dublin | 2017 |
| 40 | JH Stander (97) & G Goudie (10*) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2007 |
| 39 | MRJ Watt (57*) & MD Rao (5) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2016 |
| 36 | TJ Buchan (17*) & CS MacLeod (18) | Scotland Under-23s v Scottish National Cricket League Select XI | Hamilton Crescent, Glasgow | 2005 |
| 36 | RT Lyons (28*) & PJC Hoffmann (19) | Scotland v Barbados XI | Three Ws Oval, Cave Hill | 2006/07 |
| 36 | AJL Baum (53*) & C Gosain (0) | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 36 | PL Mommsen (31*) & CG Burnett (25) | Scotland v Lancashire | Titwood, Glasgow | 2013 |
| 36 | MRJ Watt (45*) & SM Sharif (15) | Scotland v United Arab Emirates Falcons | Dubai Sports City Stadium, Dubai | 2023/24 |
| 34 | JR Goodall (7*) & D Ormiston (28) | Scotland B v Leicestershire Second XI | Coventry Road, Lutterworth | 1984 |
| 34* | KJ Coetzer (23*) & HS Grewal (12*) | Scotland B v Marylebone Cricket Club | Savile Park, Castleford | 2001 |
| 34 | JAM Kerr (15*) & HS Grewal (17) | Scotland B v Durham Second XI | Preston Avenue, North Shields | 2002 |
| 32* | H Aslam (15*) & GSK Thomson (11*) | Scotland Development XI v Durham Academy | Myreside, Edinburgh | 2013 |
| 31* | GI Maiden (22*) & JAR Blain (19*) | Scotland v Papua New Guinea | Kaiteur Cricket Club, Kitchener | 2001 |
| 31 | AHJ Hislop (28) & TJ Buchan (4*) | Scotland A v Derbyshire Second XI | North Road, Glossop | 2009 |
| 28 | RAJ Smith (45) & BTJ Wheal (15*) | Scotland XI v Marylebone Cricket Club | Titwood, Glasgow | 2015 |
| 27 | DE Budge (151) & EE Ruthven (1*) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2018 |
| 24 | MM Iqbal (18*) & G Goudie (19) | Scotland A v Lancashire Second XI | Boughton Hall Avenue, Chester | 2012 |
| 23 | MS Richardson (26) & S Wilson (9*) | Scotland XI v Zimbabwe Cricket Union President's XI | Harare Sports Club, Harare | 1993/94 |
| 23 | NJ MacRae (27*) & SD Weeraratna (9) | Scotland A v Yorkshire Second XI | The Playing Field, Stamford Bridge | 2007 |
| 22 | JD Knight (46) & NF MacLeod (2*) | Scotland B v Durham | Philiphaugh, Selkirk | 1980 |
| 22* | JAR Blain (13*) & GA Rogers (7*) | Scotland v Bangladesh | Three Ws Oval, Cave Hill | 2006/07 |
| 20 | KW Stirling (76) & C Gosain (3*) | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 19 | JW Govan (19) & JAR Blain (7*) | Scotland B v Star Club of India | Titwood, Glasgow | 1996 |
| 19 | CC MacKellar (13) & PA Jack (0*) | Scotland B v Durham Second XI | Longhirst Hall Ground, Longhirst | 1999 |
| 19* | GD Drummond (15*) & RM Haq (11*) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 19 | G Goudie (16) & SM Sharif (4*) | Scotland A v Derbyshire Second XI | The Copper Yard, Denby Village | 2012 |
| 19* | I Wardlaw (18*) & GT Main (7*) | Scotland A v Durham Second XI | The Racecourse, Durham | 2014 |
| 19 | RM Haq (10*) & AC Evans (9) | Scotland v New Zealand XI | Bert Sutcliffe Oval, Lincoln | 2014/15 |
| 19* | A Walsh (28*) & JD Park (1*) | St George v Scotland | Hurstville Oval, Sydney | 2014/15 |
| 18 | NW Smith (29*) & RG Brown (0) | Scotland Development XI v Gloucestershire Second XI | County Ground, Bristol | 2013 |
| 18 | MRJ Watt (14*) & I Wardlaw (3) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2014 |
| 17 | [unknown] & [unknown] | Scotland XI v Royal Australian Air Force | Hamilton Crescent, Glasgow | 1945 |
| 17* | MJD Allingham (5*) & CT McKnight (11*) | Scotland B v Durham University | The Racecourse, Durham | 1990 |
| 17 | DJ Haggo (24*) & JD Moir (5) | Scotland XI v W Isaacs' XI | Country Park, Johannesburg | 1991/92 |
| 17* | IM Stanger (11*) & JAR Blain (6*) | Scotland v Glostrup | Solvangs Park, Glostrup | 1996 |
| 17 | AHJ Hislop (27) & CR Anderson (12*) | Scotland Under-23s v Netherlands Under-23s | The Inch, Dublin | 2006 |
| 16 | CD Wallace (56*) & H Tahir (10) | Scotland A v Ireland Wolves | Forthill, Dundee | 2018 |
| 16 | GT Main (20) & H Tahir (3*) | Scotland A v Ireland Wolves | Forthill, Dundee | 2018 |
| 15 | GI Maiden (18*) & G Goudie (8) | Scotland A v Durham Second XI | Station Road, Norton | 2008 |
| 15 | RM Haq (21) & AC Evans (4*) | Scotland A v Cavaliers | Bothwell Castle, Uddingston | 2011 |
| 15 | SM Sharif (13*) & TJ Buchan (3) | Scotland v Namibia | Windhoek High School, Windhoek | 2011/12 |
