| 235 | [unknown] & [unknown] | Scotland A v Yorkshire Second XI | North Marine Road, Scarborough | 2014 |
| 172 | DH Johnston (44) & O Henry (118*) | Scotland B v Leicestershire Second XI | Grace Road, Leicester | 1986 |
| 167 | CJO Smith (155*) & AC Speirs (60) | Scotland B v Durham University Second XI | The Racecourse, Durham | 1999 |
| 126 | DA Orr (98) & JW Govan (53) | Scotland B v Durham University | The Racecourse, Durham | 1996 |
| 97 | MH Cross (42) & CD Wallace (94) | Scotland A v Northamptonshire Second XI | West Lodge Park, Desborough | 2012 |
| 87 | MA Leask (119) & CD Wallace (33) | Scotland XI v Marylebone Cricket Club | Titwood, Glasgow | 2015 |
| 86 | RD Berrington (66) & MH Cross (39) | Scotland v West Indies | Sydney Cricket Ground, Sydney | 2014/15 |
| 86 | MH Cross (63) & SM Sharif (75*) | Scotland A v Kent and Northamptonshire Second XIs | County Ground, Northampton | 2017 |
| 85 | PL Mommsen (62*) & CD Wallace (33) | Scotland A v Durham Second XI | Emirates Durham International Cricket Ground, Chester-le-Street | 2013 |
| 82 | AB Russell (71) & D Fleming (16) | Scotland B v Lancashire Second XI | Old Trafford, Manchester | 1987 |
| 78* | MH Cross (56*) & SM Sharif (43*) | Scotland A v Kent and Northamptonshire Second XIs | County Ground, Northampton | 2016 |
| 75 | SD Gilmour (42) & JAM Kerr (46*) | Scotland B v Marylebone Cricket Club | Titwood, Glasgow | 2003 |
| 75 | R Henry (38) & MRJ Watt (68) | Scotland A v Ireland Wolves | Claremont Road, Dublin | 2017 |
| 72* | JG Williamson (69*) & CJO Smith (9*) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1998 |
| 71 | DF Watts (111) & GI Maiden (37) | Scotland B v Marylebone Cricket Club | Denis Compton Oval, Shenley | 2004 |
| 70 | G Salmond (45) & MJ Clark (34) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1996 |
| 70 | ST Knox (70) & JH Stander (50) | Scotland A v Leicestershire Second XI | Wilson Field, Oakham School | 2007 |
| 70 | DE Budge (56) & R Henry (45) | Scotland A v Lancashire Second XI | Parkgate, Neston | 2018 |
| 68 | DA Orr (35) & JW Govan (33) | Scotland B v Durham Second XI | Grangefield Road, Stockton-on-Tees | 1995 |
| 68 | RD Berrington (87) & PA Ross (42) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2011 |
| 65 | ABM Ker (34*) & WDG Loudon (32) | Scotland XI v Worcestershire | County Ground, New Road, Worcester | 1982 |
| 63 | CS MacLeod (31) & CD Wallace (30) | Scotland A v Derbyshire Second XI | The Copper Yard, Denby Village | 2012 |
| 63* | DE Budge (65*) & MM English (12*) | Scotland A v Lancashire Second XI | Parkgate, Neston | 2018 |
| 62* | DA Orr (32*) & JW Govan (31*) | Scotland XI v Bellville Invitation XI | PP Smit Stadium, Bellville, Cape Town | 1992/93 |
| 62 | MM Iqbal (78) & RML Taylor (25) | Scotland v Canterbury Country | MainPower Oval, Rangiora | 2013/14 |
| 61 | IL Philip (33) & W Morton (57) | Scotland B v Durham University | The Racecourse, Durham | 1990 |
| 60 | JG Williamson (13) & O Henry (84) | Scotland B v Leicestershire Second XI | Grace Road, Leicester | 1988 |
| 60 | JG Williamson (42) & DJ Haggo (15) | Scotland B v Durham Second XI | Denton Bank, Benwell Hill | 1993 |
| 60 | JH Stander (32) & WJ Rowan (26) | Scotland A v Italy | Farmers Cricket Club Ground, St Martin | 2010 |
| 59 | RO Hussain (121) & RM Haq (25) | Scotland A v Yorkshire Second XI | The Playing Field, Stamford Bridge | 2007 |
| 59 | [unknown] & [unknown] | Scotland XI v United Arab Emirates | Dubai Sports City Stadium, Dubai | 2010/11 |
| 57 | CJO Smith (48*) & CM Wright (39) | Scotland v Dorset | Hamilton Crescent, Glasgow | 1999 |
| 56 | RC Smith (42) & JG Williamson (23) | Scotland B v Nottinghamshire Second XI | Trent Bridge, Nottingham | 1990 |
| 56 | MA Mudie (23) & JG Williamson (81) | Scotland B v Star Club of India | Titwood, Glasgow | 1994 |
| 56* | SR Kennedy (42*) & MJ Clark (26*) | Scotland B v Durham Second XI | Langwell Crescent, Ashington | 1994 |
| 56 | MA Leask (80) & R Henry (19) | Scotland A v Ireland Wolves | Forthill, Dundee | 2018 |
| 56 | MM English (108) & JW Dickinson (11) | Scotland A v Northamptonshire Second XI | Campbell Park, Milton Keynes | 2018 |
| 55 | MJD Allingham (43*) & DJ Haggo (30) | Scotland XI v Northern Transvaal League | Berea Park, Pretoria | 1991/92 |
| 55 | UA Mohammad (43) & GD Drummond (30) | Scotland B v Star Club of India | Titwood, Glasgow | 2004 |
| 55 | NFI McCallum (47*) & GI Maiden (24) | Scotland XI v United Arab Emirates | Dubai Sports City Stadium, Dubai | 2010/11 |
| 55 | KJ Coetzer (83) & JH Davey (18) | Scotland v Canterbury | Hagley Oval, Christchurch | 2014/15 |
| 55 | MA Jones (173*) & TB Sole (33) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2017 |
| 54 | JS Carrick (57) & W Neilson (28) | Scotland XI v England XI | Hamilton Crescent, Glasgow | 1891 |
| 54 | IF Gavin (62) & DA Orr (66*) | Scotland B v Durham University | The Racecourse, Durham | 1992 |
| 54 | GM Hamilton (57) & CJO Smith (33) | Scotland v Tanzania | Sir Ali Muslim Club Ground, Nairobi | 2006/07 |
| 52* | CD Wallace (29*) & MA Leask (29*) | Scotland v Ireland | ICC Cricket Academy Ground No 2, Dubai | 2021/22 |
| 50 | MA Leask (56) & HG Munsey (52) | Scotland A v Durham Second XI | The Racecourse, Durham | 2014 |