| 290 | AC Storie (126) & G Salmond (165) | Scotland B v Lancashire Second XI | Hamilton Crescent, Glasgow | 1991 |
| 205 | A Brown (143) & DER Stewart (81) | Scotland XI v Durham | Philiphaugh, Selkirk | 1977 |
| 170 | HG Munsey (123) & CN Greaves (86) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2018 |
| 166 | GN Reifer (93) & IF Gavin (80) | Scotland XI v Northerns-Goodwood | Northerns-Goodwood Cricket Club Oval, Cape Town | 1992/93 |
| 162 | MA Jones (120*) & SMO Shah (61) | Scotland A v Durham Second XI | Burnopfield Cricket Club Ground, Burnopfield | 2017 |
| 140 | HJW Gardiner (109) & PL Mommsen (105*) | Scotland A v Durham Second XI | Hornby Park, Seaton Carew | 2015 |
| 137 | HJW Gardiner (84) & PL Mommsen (64) | Scotland A v Yorkshire Second XI | North Marine Road, Scarborough | 2014 |
| 136 | PL Mommsen (100*) & R Flannigan (82) | Scotland A v Leicestershire Second XI | Bath Grounds, Ashby-de-la-Zouch | 2010 |
| 130 | JGA Williams (69) & DH Johnston (61) | Scotland B v Kingfisher Colts | Nunholm, Dumfries | 1989 |
| 123 | K Farid (62) & MQ Sheikh (77) | Scotland Under-23s v Denmark Under-23s | Anglesea Road, Dublin | 2006 |
| 122 | BG Lockie (69) & GBJ McGurk (107) | Scotland B v Star Club of India | Titwood, Glasgow | 1994 |
| 121 | MM English (64*) & DE Budge (70) | Scotland XI v Marylebone Cricket Club | Titwood, Glasgow | 2015 |
| 119 | GBJ McGurk (58) & BMW Patterson (78) | Scotland B v Durham University | The Racecourse, Durham | 1989 |
| 118 | DF Watts (96) & RA Parsons (57) | Scotland B v Durham University Second XI | The Racecourse, Durham | 1998 |
| 117 | HG Munsey (98) & CS MacLeod (26) | Scotland XI v Dolphins Premier League All Stars | Hollywoodbets Kingsmead, Durban | 2019/20 |
| 109* | CS MacLeod (62*) & MW Machan (43*) | Scotland v Namibia | Sheikh Zayed Stadium, Abu Dhabi | 2013/14 |
| 108 | NJ MacRae (62) & SR Kennedy (65*) | Scotland B v Durham University | The Racecourse, Durham | 1995 |
| 106 | ST Knox (48*) & SW Dalgleish (70) | Scotland A v Leicestershire Second XI | Leicester Road, Hinckley | 2008 |
| 104 | HG Munsey (67) & CS MacLeod (36) | Scotland v Ireland | ICC Cricket Academy Ground No 2, Dubai | 2021/22 |
| 101 | DF Watts (85) & RA Keith (53) | Scotland XI v Bangladeshis | Forthill, Dundee | 1998 |
| 101 | AA Duncan (35) & D Spink (27) | Scotland B v Durham Second XI | Longhirst Hall Ground, Longhirst | 1999 |
| 99 | AG Davies (88) & DAJ Rigby (40) | Scotland B v Star Club of India | Titwood, Glasgow | 1993 |
| 99 | CS MacLeod (62) & JH Stander (116*) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 98 | BG Lockie (54) & BMW Patterson (53) | Scotland v Glostrup | Solvangs Park, Glostrup | 1996 |
| 96 | GBJ McGurk (87) & JW Govan (61) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1995 |
| 95 | BG Lockie (78) & G Salmond (37) | Scotland B v Durham University | The Racecourse, Durham | 1994 |
| 95 | DR Lockhart (47) & RR Watson (43) | Scotland XI v West Indies Select XI | Three Ws Oval, Cave Hill | 2005/06 |
| 92 | NJ MacRae (74*) & CJO Smith (61) | Scotland B v Durham University | The Racecourse, Durham | 2000 |
| 92 | EF Chalmers (30) & PL Mommsen (56) | Scotland A v Lancashire Second XI | Boughton Hall Avenue, Chester | 2012 |
| 91 | HJW Gardiner (147) & PL Mommsen (28) | Scotland A v Durham Second XI | Hornby Park, Seaton Carew | 2015 |
| 90 | R Flannigan (82) & RD Berrington (76) | Scotland A v Marylebone Cricket Club | Cambusdoon New Ground, Alloway | 2009 |
| 89 | TB Racionzer (42) & RG Swan (56) | Scotland XI v Worcestershire | County Ground, New Road, Worcester | 1980 |
| 86 | AC Storie (39) & G Salmond (57*) | Scotland XI v Techs-Mutual | The Vineyard, Cape Town | 1992/93 |
| 86 | BG Lockie (103) & RC Smith (39) | Scotland B v Durham University | The Racecourse, Durham | 1994 |
| 86 | ST Knox (103) & IM Stanger (40) | Scotland A v Lancashire Second XI | Titwood, Glasgow | 2006 |
| 86 | CD Wallace (60) & MM English (28) | Scotland A v Kent and Northamptonshire Second XIs | County Ground, Northampton | 2016 |
| 83 | DR Lockhart (28) & RA Parsons (95) | Scotland B v Durham University | The Racecourse, Durham | 1999 |
| 83 | RR Watson (64) & NS Poonia (36) | Scotland v Zimbabwe | Sedgars Park, Potchefstroom | 2007/08 |
| 80 | DR Lockhart (51) & JC Kent (71*) | Scotland XI v Durham University Centre of Cricketing Excellence Second XI | Raeburn Place, Edinburgh | 2003 |
| 80 | GI Maiden (49) & RO Hussain (26) | Scotland Academy v Guernsey | Raeburn Place, Edinburgh | 2005 |
| 80 | RR Watson (73) & KJ Coetzer (31) | Scotland v Pretoria University | LC de Villiers Oval, Pretoria | 2008/09 |
| 79 | RE McLean (31) & RD Berrington (49) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2013 |
| 79 | CS MacLeod (71) & MW Machan (48) | Scotland v Namibia | Christ's College, Christchurch | 2013/14 |
| 78 | AC Storie (41) & G Salmond (38) | Scotland B v Star Club of India | The Tryst, Stenhousemuir | 1991 |
| 78 | AJ Crosthwaite (95) & MQ Sheikh (73*) | Scotland XI v United Arab Emirates | Glenpark, Greenock | 2007 |
| 78 | DF Watts (88*) & NS Poonia (38) | Scotland v PCA Masters XI | Sir Paul Getty's Ground, Wormsley | 2009 |
| 76 | GBJ McGurk (42) & DAJ Rigby (29) | Scotland XI v Manicaland Select XI | Mutare Sports Club, Mutare | 1993/94 |