| 182 | CS MacLeod (145) & MH Cross (63) | Scotland A v Kent and Northamptonshire Second XIs | County Ground, Northampton | 2017 |
| 155 | FRJ Coleman (108) & MM Iqbal (78) | Scotland v Canterbury Country | MainPower Oval, Rangiora | 2013/14 |
| 137 | GD Phillips (106) & BJ Horne (76) | Auckland v Scotland | Kerrydale, Robina | 2017/18 |
| 126 | MA Jones (173*) & DE Budge (67) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2017 |
| 120 | [unknown] & [unknown] | Scotland XI v Leicestershire | Grace Road, Leicester | 2002 |
| 109 | TB Sole (92) & DE Budge (116*) | Scotland Development XI v Yorkshire Academy | Weetwood Playing Fields, Leeds | 2015 |
| 109 | DE Budge (87) & SMO Shah (29) | Scotland A v Bath | North Parade, Bath | 2018 |
| 106 | CS MacLeod (81) & CD Wallace (40) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2013 |
| 105 | RO Hussain (56) & RM Haq (63) | Scotland A v Yorkshire Second XI | Abbeydale Park, Sheffield | 2008 |
| 104 | RD Berrington (87) & CS MacLeod (45) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2011 |
| 103 | CM Wright (63) & SD Gilmour (51) | Scotland B v Star Club of India | Cambusdoon New Ground, Alloway | 2000 |
| 101* | IM Stanger (125*) & DR Lockhart (42*) | Scotland A v Ireland A | Cambusdoon New Ground, Alloway | 2006 |
| 98 | MW Machan (103) & RD Berrington (52) | Scotland v Ireland | Blacktown Olympic Park Oval, Sydney | 2014/15 |
| 91 | DR Brown (47) & NFI McCallum (57) | Scotland XI v Bangladesh Cricket Board Academy | Bir Shrestha Shahid Ruhul Amin Stadium, Chittagong | 2006/07 |
| 91 | MM Iqbal (70) & MA Leask (58) | Scotland A v Durham Second XI | Emirates Durham International Cricket Ground, Chester-le-Street | 2013 |
| 90 | CV English (107) & IM Stanger (40) | Scotland XI v Glamorgan | Sophia Gardens, Cardiff | 2002 |
| 89 | CJO Smith (50*) & IM Stanger (43) | Scotland B v Durham Second XI | Longhirst Hall Ground, Longhirst | 1998 |
| 85 | MQ Sheikh (53) & UA Mohammad (30) | Scotland Academy v Guernsey | Raeburn Place, Edinburgh | 2005 |
| 84 | CD Wallace (56*) & MA Leask (64) | Scotland A v Ireland Wolves | Forthill, Dundee | 2018 |
| 83 | NW Burnett (34) & DL Snodgrass (47) | Scotland B v Club Cricket Conference | Corfton Road, Ealing | 1986 |
| 83 | MJD Allingham (79) & DA Orr (34) | Scotland B v Durham Second XI | Longhirst Hall Ground, Longhirst | 1997 |
| 82 | MA Leask (119) & RD Berrington (38) | Scotland XI v Marylebone Cricket Club | Titwood, Glasgow | 2015 |
| 80* | PL Mommsen (36*) & DF Watts (52*) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 78 | JR Laing (29) & JMC Ford (65*) | Scotland XI v Denmark | Raeburn Place, Edinburgh | 1966 |
| 74 | MQ Sheikh (104) & RO Hussain (43) | Scotland A v Yorkshire Second XI | Abbeydale Park, Sheffield | 2008 |
| 72 | MQ Sheikh (103) & SJS Smith (28) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2007 |
| 72 | PL Mommsen (58*) & R Flannigan (36) | Scotland v Kolkata Knight Riders | Senwes Park, Potchefstroom | 2012/13 |
| 72 | ARI Umeed (112) & HG Munsey (37) | Scotland A v Gloucestershire Second XI | County Ground, Bristol | 2014 |
| 71 | KA McLaren (84) & RM Haq (26) | Scotland A v Ireland A | Instonians Cricket Club, Shaw's Bridge Lower Ground, Belfast | 2003 |
| 71 | RO Hussain (124*) & Asim Butt (23) | Scotland A v Lancashire Second XI | Meikleriggs, Paisley | 2006 |
| 71 | HG Munsey (39) & NAG Farrar (26) | Scotland Development XI v Northamptonshire Second XI | County Ground, Northampton | 2013 |
| 69 | RD Berrington (18) & MA Leask (54) | Scotland A v Yorkshire Second XI | North Marine Road, Scarborough | 2014 |
| 69 | RD Berrington (67*) & PL Mommsen (20) | Scotland v County XI | ICC Cricket Academy Ground, Dubai | 2015/16 |
| 66 | BMW Patterson (65) & MJD Allingham (19) | Scotland B v Nottinghamshire Second XI | Trent Bridge, Nottingham | 1990 |
| 66* | RD Berrington (61*) & PL Mommsen (15*) | Scotland v Namibia | Raeburn Place, Edinburgh | 2015 |
| 65 | RD Berrington (93) & MH Cross (42) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2015 |
| 64 | EF Chalmers (34) & PL Mommsen (42) | Scotland v Essex | The Essex County Ground, Chelmsford | 2013 |
| 64 | FRJ Coleman (59*) & NDF Flack (26) | Scotland Development XI v Yorkshire Second XI | St George's Road, Harrogate | 2016 |
| 63 | AB Russell (27) & O Henry (52) | Scotland B v Leicestershire Second XI | Coventry Road, Lutterworth | 1984 |
| 63 | NW Burnett (54*) & O Henry (44) | Scotland B v Nottinghamshire Second XI | Elm Avenue, Newark-on-Trent | 1985 |
| 63 | [unknown] & [unknown] | Scotland A v Yorkshire Second XI | North Marine Road, Scarborough | 2014 |
| 62 | [unknown] & [unknown] | Scotland XI v Gloucestershire | Greenbank, Bristol | 1924 |
| 62 | IG Kennedy (92) & JD Knight (33) | Scotland B v Central Lancashire League | Nunholm, Dumfries | 1981 |
| 62 | ARI Umeed (52) & A Bailwal (40*) | Scotland A v Warwickshire Second XI | Edgbaston, Birmingham | 2013 |
| 62 | EF Chalmers (84) & MM English (23) | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 61 | MW Machan (53*) & PL Mommsen (25) | Scotland XI v Cricket Club of India | Brabourne Stadium, Mumbai | 2015/16 |
| 60 | CJ Warner (57*) & WA Donald (15) | Scotland v West Indians | Forthill, Dundee | 1980 |
| 60 | RKP Cannon (22) & MQ Sheikh (45) | Scotland Under-23s v Northern Universities Student Club Community Cricketers Elite | Denefield Bank, Winlaton | 2006 |
| 60* | MQ Sheikh (57*) & SJS Smith (9*) | Scotland A v Durham Academy | Titwood, Glasgow | 2006 |
| 58 | NFI McCallum (101*) & CM Wright (15) | Scotland B v Durham University | The Racecourse, Durham | 2000 |
| 57 | RD Berrington (32) & PL Mommsen (30) | Scotland v Oman | Punjab Cricket Association IS Bindra Stadium, Mohali | 2015/16 |
| 56 | DN Anderson (22) & DF Watts (67) | Scotland XI v Derbyshire Second XI | Town Ground, Heanor | 2001 |
| 56 | R Flannigan (50) & GC Holmes (20) | Scotland A v Netherlands A | Hazelaarweg, Rotterdam | 2008 |
| 56 | RD Berrington (45) & MM Iqbal (48*) | Scotland A v Warwickshire Second XI | Edgbaston, Birmingham | 2013 |
| 56 | PL Mommsen (59) & CD Wallace (22) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2013 |
| 55 | PL Mommsen (42) & MM Iqbal (38) | Scotland v Derbyshire | Raeburn Place, Edinburgh | 2013 |
| 54 | IL Philip (64) & RG Swan (45) | Scotland XI v Glamorgan | Inverleith, Edinburgh | 1987 |
| 54 | KJ Coetzer (128) & PL Mommsen (30) | Scotland v Otago | Bert Sutcliffe Oval, Lincoln | 2014/15 |
| 53 | MM English (76) & SM Sharif (19) | Scotland A v Durham Second XI | Burnopfield Cricket Club Ground, Burnopfield | 2017 |
| 52 | JD Love (47) & GN Reifer (20) | Scotland XI v Durham | Ropery Lane, Chester-le-Street | 1994 |
| 52* | CJO Smith (38*) & CM Wright (25*) | Scotland XI v Denmark | Goldenacre, Edinburgh | 1997 |
| 50 | IG Kennedy (91) & NW Burnett (56*) | Scotland B v Durham University | The Racecourse, Durham | 1985 |