| Inns | HS |
| 259 | 43* | Scotland (1) v Ireland | Cambusdoon New Ground, Alloway | 2000 |
| 237 | 47 | Scotland (2) v Surrey Club | Kennington Oval, Kennington | 1865 |
| 234-8 | 48 | Scotland v Zimbabwe | Queens Sports Club, Bulawayo | 2023 |
| 231-8 | 49 | Scotland v Bermuda | Royal Selangor Club, Kuala Lumpur | 1996/97 |
| 224 | 48* | Scotland (2) v Surrey | Kennington Oval, Kennington | 1892 |
| 224 | 49* | Scotland (1) v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1934 |
| 221 | 44 | Scotland v Netherlands | Civil Service Cricket Club, Stormont, Belfast | 2005 |
| 221 | 47 | Scotland v Namibia | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 219 | 48* | Scotland (2) v Ireland | Whitehaugh Oval, Paisley | 1960 |
| 216 | 42 | Scotland v Nottinghamshire | Raeburn Place, Edinburgh | 2007 |
| 215-8 | 48 | Scotland v Leicestershire | Grace Road, Leicester | 1990 |
| 210 | 31 | Scotland v Afghanistan | University Oval, Dunedin | 2014/15 |
| 210 | 47 | Scotland v Zimbabwe | Queens Sports Club, Bulawayo | 2017/18 |
| 209-8 | 45 | Scotland v Canada | Mombasa Sports Club Ground, Mombasa | 2006/07 |
| 207-7 | 42 | Scotland v Northamptonshire | Hamilton Crescent, Glasgow | 1989 |
| 206 | 44 | Scotland v Afghanistan | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 205 | 45 | Scotland (2) v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1880 |
| 203 | 33 | Scotland v Warwickshire | Titwood, Glasgow | 1981 |
| 203-9 | 44 | Scotland v India | Titwood, Glasgow | 2007 |
| 201-8 | 47 | Scotland v Netherlands | Cambusdoon New Ground, Alloway | 2000 |
| 201-8 | 46 | Scotland v Canada | Maple Leaf North-East Ground, King City | 2001 |
| 197 | 36 | Scotland v Canada | Dubai Sports City Stadium, Dubai | 2023/24 |
| 194-8 | 45 | Scotland v Denmark | Malton Cricket Club, Toronto | 2001 |
| 193-6 | 36 | Scotland v Leicestershire | Grace Road, Leicester | 1997 |
| 193 | 45 | Scotland v Somerset | Raeburn Place, Edinburgh | 2004 |
| 193-8 | 36 | Scotland v Yorkshire | Raeburn Place, Edinburgh | 2008 |
| 192-9 | 42 | Scotland v Indians | Nunholm, Dumfries | 1986 |
| 191-9 | 48 | Scotland v Sussex | Raeburn Place, Edinburgh | 2003 |
| 191-6 | 43 | Scotland v Northamptonshire | County Ground, Northampton | 2007 |
| 190-8d | 33 | Scotland (1) v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1990 |