| 146* | CJO Smith (79*) & CV English (53*) | Scotland v Durham | Raeburn Place, Edinburgh | 2004 |
| 138 | PL Mommsen (139*) & RD Berrington (63) | Scotland v United Arab Emirates | Bert Sutcliffe Oval, Lincoln | 2013/14 |
| 136 | RS Dravid (129*) & CJO Smith (44) | Scotland v Nottinghamshire | Raeburn Place, Edinburgh | 2003 |
| 134 | BR Hardie (118) & JM Allan (45) | Scotland v Warwickshire | Edgbaston, Birmingham | 1970 |
| 133 | RD Berrington (82) & NFI McCallum (51) | Scotland v Netherlands | Sportpark Het Schootsveld, Deventer | 2010 |
| 131 | RE More (81) & DAJ Rigby (66) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2002 |
| 130 | JM Allan (58*) & D Barr (86) | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1967 |
| 130 | EF Chalmers (109) & LR Butterworth (80) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2011 |
| 119 | GM Hamilton (131) & NFI McCallum (53) | Scotland v Leicestershire | Raeburn Place, Edinburgh | 2006 |
| 118 | RR Watson (80) & NFI McCallum (68) | Scotland v Pakistan | Raeburn Place, Edinburgh | 2006 |
| 117* | J Aitchison (190*) & JM Allan (31*) | Scotland v Ireland | College Park, Dublin | 1959 |
| 117 | G Salmond (61*) & JG Williamson (57) | Scotland v West Indians | Raeburn Place, Edinburgh | 1995 |
| 114 | G Salmond (181) & MJD Allingham (50*) | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 112 | BR Hardie (118) & R Ellis (52) | Scotland v Warwickshire | Edgbaston, Birmingham | 1974 |
| 109 | J Kerr (147) & GWA Alexander (60) | Scotland v Australians | Raeburn Place, Edinburgh | 1921 |
| 106* | HG Munsey (79*) & DE Budge (40*) | Scotland v Netherlands | Hazelaarweg, Rotterdam | 2021 |
| 105 | CJO Smith (71) & GM Hamilton (43) | Scotland v Yorkshire | Headingley, Leeds | 2006 |
| 104 | JH Davey (91) & PL Mommsen (42) | Scotland v Warwickshire | Edgbaston, Birmingham | 2011 |
| 103 | RS Weir (58*) & ABM Ker (42) | Scotland v Worcestershire | Forthill, Dundee | 1982 |
| 101 | RD Berrington (110) & PL Mommsen (49*) | Scotland v Namibia | Raeburn Place, Edinburgh | 2017 |
| 100 | RR Watson (56) & CJO Smith (93) | Scotland v Kenya | Sheikh Zayed Stadium, Abu Dhabi | 2004/05 |
| 98* | J Kerr (80*) & CS Paterson (47*) | Scotland v South Africans | Raeburn Place, Edinburgh | 1924 |
| 98 | RD Berrington (97) & DE Budge (32*) | Scotland v Oman | Al Amerat Cricket Ground Turf 2, Al Amerat | 2021 |
| 97* | GM Hamilton (64*) & DR Brown (50*) | Scotland v Canada | Ruaraka Sports Club Ground, Nairobi | 2006/07 |
| 97 | MW Machan (56) & RD Berrington (50) | Scotland v New Zealand | University Oval, Dunedin | 2014/15 |
| 96 | JW Sorrie (79) & GLD Hole (67) | Scotland v Australian Imperial Forces | Raeburn Place, Edinburgh | 1919 |
| 96 | JB Jones (122) & HL Stewart (65*) | Scotland v Sir J Cahn's XI | Stanford Hall, Stanford | 1935 |
| 94 | GBJ McGurk (34) & GN Reifer (73*) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1994 |
| 93 | W Nichol (93) & WR Heggie (38) | Scotland v Yorkshire | Hamilton Crescent, Glasgow | 1946 |
| 93 | GJ Bailey (70) & NFI McCallum (45) | Scotland v Kent | St Lawrence Ground, Canterbury | 2010 |
| 91 | JA Beukes (92) & CV English (40) | Scotland v Somerset | County Ground, Taunton | 2005 |
| 90 | BMW Patterson (36*) & O Henry (69) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1988 |
| 90 | RG Swan (53) & O Henry (62*) | Scotland v Nottinghamshire | Titwood, Glasgow | 1990 |
| 90 | G Salmond (46) & JE Brinkley (34) | Scotland v Ireland | Ormeau, Belfast | 1999 |
| 90 | RR Watson (66) & DF Watts (55*) | Scotland v Denmark | Hazelaarweg, Rotterdam | 2004 |