| Inns | HS |
| 323-5 | 89 | Scotland v Ireland | Raeburn Place, Edinburgh | 2011 |
| 307-9 | 74 | Scotland v Ireland | ICC Cricket Academy Ground, Dubai | 2017/18 |
| 306 | 85 | Scotland v New Zealand | Raeburn Place, Edinburgh | 2022 |
| 299-9 | 90 | Scotland v United Arab Emirates | ICC Cricket Academy Ground, Dubai | 2017/18 |
| 290-9 | 91 | Scotland v Namibia | Forthill, Dundee | 2024 |
| 289-9 | 91* | Scotland v Ireland | Queens Sports Club, Bulawayo | 2023 |
| 287-5 | 74 | Scotland v Papua New Guinea | Dubai Sports City Stadium, Dubai | 2022 |
| 276-4 | 70 | Scotland v Canada | Ruaraka Sports Club Ground, Nairobi | 2006/07 |
| 273-6 | 97 | Scotland v Oman | Al Amerat Cricket Ground Turf 2, Al Amerat | 2021 |
| 268-9 | 79 | Scotland v Bermuda | Ruaraka Sports Club Ground, Nairobi | 2006/07 |
| 262 | 76 | Scotland v United Arab Emirates | Mannofield Park, Aberdeen | 2022 |
| 261-7 | 78 | Scotland v Kenya | Hagley Oval, Christchurch | 2013/14 |
| 258-6 | 71* | Scotland v Namibia | Titwood, Glasgow | 2022 |
| 255-7 | 64 | Scotland v Netherlands | Mannofield Park, Aberdeen | 2011 |
| 254-8 | 71 | Scotland v Kenya | Gymkhana Club Ground, Nairobi | 2006/07 |
| 254-9 | 85 | Scotland v United Arab Emirates | Mannofield Park, Aberdeen | 2022 |
| 253-8 | 59 | Scotland v Kenya | Mombasa Sports Club Ground, Mombasa | 2006/07 |
| 253-5 | 79* | Scotland v Canada | Mannofield Park, Aberdeen | 2009 |
| 247 | 86 | Scotland v United States of America | Sharjah Cricket Association Stadium, Sharjah | 2019/20 |
| 246 | 61 | Scotland v Ireland | Harare Sports Club, Harare | 2017/18 |
| 246-6 | 62 | Scotland v United States of America | ICC Cricket Academy Ground, Dubai | 2019/20 |
| 242-7 | 81 | Scotland v Papua New Guinea | Mannofield Park, Aberdeen | 2019 |
| 237-8 | 96 | Scotland v Afghanistan | ICC Cricket Academy Ground, Dubai | 2014/15 |
| 236-4 | 89* | Scotland v Canada | VRA Ground, Amstelveen | 2010 |
| 235-6 | 84 | Scotland v Netherlands | Hazelaarweg, Rotterdam | 2010 |
| 235-9 | 63 | Scotland v Netherlands | VRA Ground, Amstelveen | 2010 |
| 234-8 | 48 | Scotland v Zimbabwe | Queens Sports Club, Bulawayo | 2023 |
| 232 | 98 | Scotland v Ireland | VRA Ground, Amstelveen | 2010 |
| 228-6 | 81 | Scotland v Papua New Guinea | Al Amerat Cricket Ground, Al Amerat | 2021 |
| 226-8 | 73 | Scotland v Oman | Dubai Sports City Stadium, Dubai | 2022 |