| 205 | NJ MacRae (143) & NFI McCallum (117*) | Scotland A v Durham Academy | Titwood, Glasgow | 2006 |
| 193 | AC Storie (142) & GBJ McGurk (112) | Scotland B v Durham University | The Racecourse, Durham | 1996 |
| 144 | NJ MacRae (98) & DR Lockhart (107*) | Scotland B v Durham Second XI | Grangefield Road, Stockton-on-Tees | 1995 |
| 141 | CS MacLeod (74) & RD Berrington (145) | Scotland v Auckland | Kerrydale, Robina | 2017/18 |
| 136 | RG Swan (75) & O Henry (106*) | Scotland XI v Worcestershire | County Ground, New Road, Worcester | 1985 |
| 136 | RA Keith (61) & RA Parsons (84) | Scotland B v Durham Second XI | Longhirst Hall Ground, Longhirst | 1998 |
| 136* | CS MacLeod (129*) & FRJ Coleman (39*) | Scotland v St George | Hurstville Oval, Sydney | 2014/15 |
| 136 | MA Jones (76) & MM English (67) | Scotland A v Ireland Wolves | Claremont Road, Dublin | 2017 |
| 121 | R Flannigan (123*) & IDK Young (54) | Scotland A v Scotland Under-19s | Bothwell Castle, Uddingston | 2009 |
| 119 | SC Coetzer (98) & DF Watts (111) | Scotland B v Marylebone Cricket Club | Denis Compton Oval, Shenley | 2004 |
| 119 | PL Mommsen (66) & SJ Chalmers (74) | Scotland A v Delhi Under-19s | Titwood, Glasgow | 2009 |
| 118 | K Scott (203) & G Lawrence (62) | Scotland B v Durham University | Lochside Park, Forfar | 1984 |
| 112 | DF Watts (80) & RO Hussain (62) | Scotland A v Marylebone Cricket Club | Titwood, Glasgow | 2006 |
| 112 | JR Edwards (81) & PA Ross (53) | Scotland Development XI v Yorkshire Academy | Weetwood Playing Fields, Leeds | 2013 |
| 110 | GN Reifer (49) & RA Parsons (117) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1995 |
| 104 | GBJ McGurk (74) & SR Kennedy (17) | Scotland B v Durham Second XI | Denton Bank, Benwell Hill | 1993 |
| 104 | IM Stanger (125*) & MQ Sheikh (53) | Scotland A v Ireland A | Cambusdoon New Ground, Alloway | 2006 |
| 101 | EF Chalmers (86) & RD Berrington (126) | Scotland A v Northamptonshire Second XI | West Lodge Park, Desborough | 2012 |
| 99 | R Flannigan (65) & SJ Chalmers (67) | Scotland A v Scotland Under-19s | Bothwell Castle, Uddingston | 2009 |
| 97 | ST Knox (65) & MQ Sheikh (79) | Scotland A v Durham Second XI | Station Road, Norton | 2008 |
| 97 | HJW Gardiner (32) & DE Budge (105) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2015 |
| 93* | J Aitchison (64*) & JRN Taylor (27*) | Scotland XI v Army XI | Raeburn Place, Edinburgh | 1949 |
| 93 | MW Machan (64) & FRJ Coleman (53) | Scotland v Canterbury Country | MainPower Oval, Rangiora | 2013/14 |
| 90 | FRJ Coleman (63) & CS MacLeod (55) | Scotland v Lancashire | Emirates Old Trafford, Manchester | 2013 |
| 90 | RR O'Donnell (57) & C Cachopa (75) | Auckland v Scotland | Kerrydale, Robina | 2017/18 |
| 88 | DH Johnston (47) & G Salmond (35) | Scotland B v Kingfisher Colts | Nunholm, Dumfries | 1989 |
| 88 | KJ Coetzer (66) & PL Mommsen (65) | Scotland v Wellington | Bert Sutcliffe Oval, Lincoln | 2014/15 |
| 83 | RD Berrington (68) & KJ Coetzer (23) | Scotland v Sri Lanka Ports Authority Cricket Club | Moors Sports Club Ground, Colombo | 2013/14 |
| 82 | HG Munsey (68) & MM English (31) | Scotland A v Gloucestershire Second XI | North Parade, Bath | 2017 |
| 82 | MM English (110) & MA Leask (39) | Scotland A v Bath | North Parade, Bath | 2018 |
| 80 | SD Gilmour (37) & CJO Smith (63) | Scotland B v Marylebone Cricket Club | Savile Park, Castleford | 2001 |
| 79 | SC Coetzer (37) & NFI McCallum (97) | Scotland A v Durham Second XI | Raeburn Place, Edinburgh | 2006 |
| 77 | NJ MacRae (44) & RC Smith (57) | Scotland B v Star Club of India | Titwood, Glasgow | 1994 |
| 77* | IL Philip (52*) & RA Parsons (43*) | Scotland XI v Bangladeshis | Forthill, Dundee | 1998 |
| 77 | DF Watts (128) & KA McLaren (15) | Scotland B v Marylebone Cricket Club | Titwood, Glasgow | 2003 |
| 75 | EF Chalmers (57) & MQ Sheikh (38) | Scotland A v Italy | Farmers Cricket Club Ground, St Martin | 2010 |
| 72 | GM Hamilton (52) & NS Poonia (38) | Scotland v Kenya | Willowmoore Park B Field, Benoni | 2008/09 |
| 71 | CJO Smith (50) & SD Gilmour (44) | Scotland B v Durham University | The Racecourse, Durham | 2000 |
| 70 | MQ Sheikh (67) & EF Chalmers (26) | Scotland A v Denmark A | VRA Ground, Amstelveen | 2009 |
| 69 | MA Jones (46) & R Henry (39) | Scotland Development XI v Yorkshire Second XI | St George's Road, Harrogate | 2016 |
| 68 | NJ MacRae (43) & G Salmond (92) | Scotland B v Durham University | The Racecourse, Durham | 1995 |
| 66 | SC Coetzer (54) & RM Haq (34) | Scotland Under-23s v Scottish National Cricket League Select XI | Hamilton Crescent, Glasgow | 2005 |
| 65 | DH Johnston (29) & MJ Smith (32) | Scotland B v Leicestershire Second XI | Grace Road, Leicester | 1988 |
| 65 | DR Lockhart (48) & RA Parsons (66) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1996 |
| 65* | SD Gilmour (41*) & NFI McCallum (26*) | Scotland B v Yorkshire Academy | Windy Hill Lane, Marske-by-the-Sea | 2000 |
| 65 | ARI Umeed (112) & RD Berrington (38) | Scotland A v Gloucestershire Second XI | County Ground, Bristol | 2014 |
| 64 | GM Hamilton (49) & DF Watts (29) | Scotland XI v Empire | Police Sports Club Ground, Bridgetown | 2005/06 |
| 63* | ABM Ker (25*) & WA Donald (38*) | Scotland B v Central Lancashire League | Nunholm, Dumfries | 1979 |
| 62 | DF Watts (85) & RA Parsons (29) | Scotland XI v Bangladeshis | Forthill, Dundee | 1998 |
| 62 | RD Berrington (39) & CS MacLeod (33) | Scotland v Durham | Titwood, Glasgow | 2013 |
| 62 | MW Machan (67) & PL Mommsen (19*) | Scotland v Papua New Guinea | St Andrew's College Ground, Christchurch | 2013/14 |
| 62 | MA Jones (120*) & CS MacLeod (39) | Scotland A v Durham Second XI | Burnopfield Cricket Club Ground, Burnopfield | 2017 |
| 61 | RM Haq (17) & RD Berrington (49) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2014 |
| 60 | IG Kennedy (91) & AB Russell (17) | Scotland B v Durham University | The Racecourse, Durham | 1985 |