| 257 | K Scott (203) & DJ Simpson (120) | Scotland B v Durham University | Lochside Park, Forfar | 1984 |
| 206 | HJW Gardiner (90) & RE McLean (108) | Scotland Development XI v Northamptonshire Second XI | County Ground, Northampton | 2013 |
| 194 | STT Wilkinson (96*) & ABM Ker (93) | Scotland B v Central Lancashire League | The Paddock, Royton | 1980 |
| 192 | GL Willatt (75) & TR Crosskey (120) | Scotland XI v Army XI | Raeburn Place, Edinburgh | 1949 |
| 179 | IL Philip (72) & AC Storie (101*) | Scotland XI v Barbados | Titwood, Glasgow | 1993 |
| 169 | AC Storie (85) & BG Lockie (88) | Scotland B v Netherlands | Goldenacre, Edinburgh | 1995 |
| 162 | KJ Coetzer (80) & CS MacLeod (82) | Scotland v Canterbury Country | MainPower Oval, Rangiora | 2013/14 |
| 155 | SMO Shah (78) & MM English (100) | Scotland A v Ireland Wolves | Forthill, Dundee | 2018 |
| 148 | ARI Umeed (68) & HJW Gardiner (85) | Scotland XI v United Arab Emirates | The Ageas Bowl, Southampton | 2015 |
| 143 | DR Lockhart (103) & IM Stanger (61) | Scotland v Durham | Riverside Ground, Chester-le-Street | 2006 |
| 141 | BG Lockie (55) & ST Crawley (109*) | Scotland v Nottinghamshire Cricket Board | Boghall, Linlithgow | 1999 |
| 131* | R Flannigan (20*) & CS MacLeod (100*) | Scotland A v Cavaliers | Bothwell Castle, Uddingston | 2011 |
| 129 | OJ Hairs (108) & R Flannigan (38) | Scotland A v Warwickshire Second XI | Rugby School Ground, Rugby | 2010 |
| 126 | NJ MacRae (67) & DR Lockhart (65) | Scotland B v Durham Second XI | Langwell Crescent, Ashington | 1994 |
| 116* | RE More (54*) & SA Murray (48*) | Scotland A v Denmark A | Sportpark Het Schootsveld, Deventer | 2002 |
| 115 | BG Lockie (103) & NJ MacRae (44) | Scotland B v Durham University | The Racecourse, Durham | 1994 |
| 114 | ARI Umeed (64) & HJW Gardiner (54) | Scotland XI v United Arab Emirates | The Ageas Bowl, Southampton | 2015 |
| 109 | R Flannigan (82) & MQ Sheikh (59) | Scotland A v Marylebone Cricket Club | Cambusdoon New Ground, Alloway | 2009 |
| 105 | SA Murray (29) & RM Haq (68) | Scotland A v Durham Academy | Raeburn Place, Edinburgh | 2007 |
| 104 | DF Watts (58) & D Spink (50) | Scotland B v Yorkshire Academy | Windy Hill Lane, Marske-by-the-Sea | 2000 |
| 100 | GBJ McGurk (44) & JGA Williams (52) | Scotland B v Durham University | The Racecourse, Durham | 1989 |
| 98 | SA Murray (40) & AJ Crosthwaite (95) | Scotland XI v United Arab Emirates | Glenpark, Greenock | 2007 |
| 95 | DJ Simpson (38) & RR Jones (51) | Scotland B v Durham University | The Racecourse, Durham | 1982 |
| 94 | RE More (38) & DF Watts (44) | Scotland A v Denmark A | Osborne Park, Belfast | 2003 |
| 94 | HJW Gardiner (48) & FRJ Coleman (53) | Scotland v Surrey | The Kia Oval, Kennington | 2013 |
| 92 | WR Scarff (33) & TB Racionzer (44) | Scotland XI v Worcestershire | County Ground, New Road, Worcester | 1981 |
| 92 | K Scott (45) & GBJ McGurk (42) | Scotland B v Leicestershire Second XI | Grace Road, Leicester | 1988 |
| 92* | ST Knox (35*) & R Flannigan (48*) | Scotland A v Denmark A | Hazelaarweg, Rotterdam | 2008 |
| 91 | RG Swan (24) & ABM Ker (61) | Scotland B v Durham | Philiphaugh, Selkirk | 1980 |
| 90 | BG Lockie (43) & DR Lockhart (47) | Scotland B v Denmark | Raeburn Place, Edinburgh | 1995 |
| 90 | DR Lockhart (42) & MQ Sheikh (54) | Scotland A v Yorkshire Second XI | Weetwood Playing Fields, Leeds | 2009 |
| 87* | SA Murray (31*) & RM Haq (40*) | Scotland A v Scotland Under-19s | Cambusdoon New Ground, Alloway | 2004 |
| 85 | AM Zuill (46) & ID Stevenson (39) | Scotland B v British Police | Ferryfield, Edinburgh | 1975 |
| 83 | ST Knox (51) & DF Watts (50) | Scotland XI v Durham University Centre of Cricketing Excellence Second XI | Raeburn Place, Edinburgh | 2005 |
| 83 | HJW Gardiner (33) & CS MacLeod (41) | Scotland A v Durham Second XI | Emirates Durham International Cricket Ground, Chester-le-Street | 2013 |
| 83 | MH Cross (59) & KJ Coetzer (54) | Scotland v Netherlands | Groenkloof Oval, Pretoria | 2017/18 |
| 80 | AM Zuill (63) & TN Gallacher (27) | Scotland XI v New Zealand Cricket Council XI | Whitehaugh Oval, Paisley | 1964 |
| 80 | HJW Gardiner (147) & ARI Umeed (32) | Scotland A v Durham Second XI | Hornby Park, Seaton Carew | 2015 |
| 79 | DR Lockhart (33) & PL Mommsen (100*) | Scotland A v Leicestershire Second XI | Bath Grounds, Ashby-de-la-Zouch | 2010 |
| 79 | HJW Gardiner (32) & CS MacLeod (43) | Scotland A v Durham Second XI | The Racecourse, Durham | 2014 |
| 78 | AC Storie (21) & GBJ McGurk (56) | Scotland B v Lancashire Second XI | Hamilton Crescent, Glasgow | 1992 |
| 78 | GBJ McGurk (37) & AA Docherty (63) | Scotland XI v C Barnes' XI | Harare Sports Club, Harare | 1993/94 |
| 78 | HG Munsey (86) & KJ Coetzer (15) | Scotland v Ireland | Sheikh Zayed Stadium Nursery 1, Abu Dhabi | 2019/20 |
| 76 | NS Poonia (46) & RM Haq (37) | Scotland Under-23s v Northern Universities Student Club Community Cricketers Elite | Denefield Bank, Winlaton | 2006 |
| 75 | RD Berrington (27) & CS MacLeod (84) | Scotland v Ragama Cricket Club | Nondescripts Cricket Club Ground, Colombo | 2013/14 |
| 75 | KJ Coetzer (96) & CS MacLeod (32) | Scotland v West Indies | Sydney Cricket Ground, Sydney | 2014/15 |
| 75 | HJW Gardiner (109) & ARI Umeed (32) | Scotland A v Durham Second XI | Hornby Park, Seaton Carew | 2015 |