| 170 | RO Hussain (121) & RT Lyons (100) | Scotland A v Yorkshire Second XI | The Playing Field, Stamford Bridge | 2007 |
| 85* | CM Wright (78*) & SD Weeraratna (30*) | Scotland A v Marylebone Cricket Club | Titwood, Glasgow | 2006 |
| 73 | SJS Smith (61*) & SD Weeraratna (50) | Scotland A v Derbyshire Second XI | Christchurch Meadows, Belper | 2008 |
| 72 | KW Stirling (76) & GT Main (20) | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 67 | O Henry (117) & DD Cavellini (11) | Scotland B v Nottinghamshire Second XI | Nottingham High School Ground, Nottingham | 1984 |
| 63 | MA Jones (173*) & AC Evans (14) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2017 |
| 62 | MA Parker (34) & SD Weeraratna (70*) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2008 |
| 57 | R Flannigan (49) & G Goudie (9) | Scotland A v Cavaliers | Bothwell Castle, Uddingston | 2011 |
| 55* | MS Richardson (41*) & CT McKnight (17*) | Scotland B v Nottinghamshire Second XI | Trent Bridge, Nottingham | 1990 |
| 54 | PG Duthie (63) & DD Cavellini (15) | Scotland B v Leicestershire Second XI | Coventry Road, Lutterworth | 1984 |
| 53* | JG Williamson (21*) & KLP Sheridan (23*) | Scotland B v Star Club of India | The Tryst, Stenhousemuir | 1992 |
| 52 | DR Brown (36) & JD Nel (43) | Scotland v Barbados XI | Three Ws Oval, Cave Hill | 2006/07 |
| 50 | SM Sharif (64) & MRJ Watt (14) | Scotland Development XI v Yorkshire Academy | Weetwood Playing Fields, Leeds | 2013 |
| 50 | HG Munsey (52) & RM Haq (14) | Scotland A v Durham Second XI | The Racecourse, Durham | 2014 |
| 50 | MH Cross (64*) & RML Taylor (26) | Scotland v Tasmania | Anzac Park, Hobart | 2014/15 |
| 48* | O Henry (45*) & AD MacPherson (8*) | Scotland B v Durham University | The Racecourse, Durham | 1986 |
| 48 | K Scott (75) & JW Govan (19) | Scotland B v Durham University | The Racecourse, Durham | 1987 |
| 47* | DR Lockhart (22*) & MA Parker (18*) | Scotland v Afghanistan | Sportpark Westvliet, Voorburg | 2010 |
| 46 | CM Wright (17) & JAR Blain (30) | Scotland XI v West Indies Select XI | Three Ws Oval, Cave Hill | 2005/06 |
| 46 | JW Dickinson (32*) & A Sabri (32) | Scotland A v Bath | North Parade, Bath | 2018 |
| 44 | JE Ker (16) & PA Rhind (36) | Scotland XI v Durham | Philiphaugh, Selkirk | 1977 |
| 43* | NW Burnett (27*) & D Fleming (11*) | Scotland B v Leicestershire Second XI | Grace Road, Leicester | 1987 |
| 41 | IM Stanger (43) & MM Iqbal (21) | Scotland XI v Northamptonshire | County Ground, Northampton | 2002 |
| 41 | MA Leask (62) & SM Sharif (22*) | Scotland XI v United Arab Emirates | The Ageas Bowl, Southampton | 2015 |
| 40 | JG Williamson (81) & CJ Mearns (4) | Scotland B v Star Club of India | Titwood, Glasgow | 1994 |
| 39* | EJ McIntyre (14*) & WA McPate (27*) | Scotland B v Scottish Cricket Union President's XI | Hamilton Crescent, Glasgow | 1982 |
| 39 | MA Mudie (34) & G Salmond (37*) | Scotland B v Durham Second XI | Longhirst Hall Ground, Longhirst | 1997 |
| 39 | RT Lyons (34) & CG Burnett (20) | Scotland A v Yorkshire Second XI | Weetwood Playing Fields, Leeds | 2009 |
| 39 | FRJ Coleman (51) & RML Taylor (18) | Scotland v Queensland Academy of Sport | John Blanck Oval, Maroochydore | 2014/15 |
| 37 | EF Chalmers (61) & MJ Petrie (25*) | Scotland A v Ireland A | Grainville, St Saviour | 2010 |
| 36 | G Salmond (120*) & NR Dyer (1) | Scotland B v Yorkshire Second XI | Park Avenue Cricket Ground, Bradford | 1997 |
| 36 | JAR Blain (40) & JD Nel (11) | Scotland XI v Empire | Police Sports Club Ground, Bridgetown | 2005/06 |
| 36 | PA Ross (42) & SJS Smith (15) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2011 |
| 36 | MA Leask (40*) & SM Sharif (15) | Scotland v Canterbury Country | MainPower Oval, Rangiora | 2013/14 |
| 35 | JW Govan (16) & W Morton (34) | Scotland B v Lancashire Second XI | Old Trafford, Manchester | 1988 |
| 35 | DA Orr (98) & KLP Sheridan (9*) | Scotland B v Durham University | The Racecourse, Durham | 1996 |
| 34 | RAJ Smith (45) & H Aslam (9) | Scotland XI v Marylebone Cricket Club | Titwood, Glasgow | 2015 |
| 33 | HS Grewal (26*) & MDC Ferguson (18) | Scotland A v Scotland Under-19s | Cambusdoon New Ground, Alloway | 2004 |
| 33 | CM Wright (47*) & JH Stander (8) | Scotland v Kenya | Willowmoore Park B Field, Benoni | 2008/09 |
| 32 | O Henry (34*) & AD MacPherson (7) | Scotland B v Durham University | The Racecourse, Durham | 1986 |
| 32 | MA Parker (23) & G Goudie (30*) | Scotland A v Derbyshire Second XI | Christchurch Meadows, Belper | 2008 |
| 32 | HJW Gardiner (147) & CAR MacLeod (11) | Scotland A v Durham Second XI | Hornby Park, Seaton Carew | 2015 |
| 32* | MH Cross (27*) & CR Garden (5*) | Scotland A v Lancashire Second XI | Parkgate, Neston | 2018 |
| 31 | JG Williamson (39) & MA Mudie (0) | Scotland XI v Mashonaland Select XI | Alexandra Sports Club, Harare | 1993/94 |
| 31 | SD Gilmour (25) & SJ Davidson (13) | Scotland B v Durham Second XI | Preston Avenue, North Shields | 2002 |
| 31* | [unknown] & [unknown] | Scotland XI v United Arab Emirates | Dubai Sports City Stadium, Dubai | 2010/11 |
| 30* | [unknown] & [unknown] | Scotland XI v Durham | Ropery Lane, Chester-le-Street | 1993 |
| 30 | CJO Smith (72*) & Jalees Ahmed (9) | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2001 |