| 58 | RJ Pope | Gentlemen of Scotland v Gentlemen of Canada | Raeburn Place, Edinburgh | 1887 |
| 88* | CT Mannes | Scotland XI v A Shrewsbury's XI | Hamilton Crescent, Glasgow | 1890 |
| 57 | JS Carrick | Scotland XI v England XI | Hamilton Crescent, Glasgow | 1891 |
| 63 | RJH Lambert | Scotland XI v Dublin University | College Park, Dublin | 1898 |
| 72 | DA Mackay | Scotland XI v Ireland XI | Mannofield Park, Aberdeen | 1930 |
| 85* | IJM Lumsden | Scotland XI v LN Constantine's XI | The Tryst, Stenhousemuir | 1945 |
| 59 | J Aitchison | Scotland XI v HB Rowan's Empire XI | Hamilton Crescent, Glasgow | 1945 |
| 120 | TR Crosskey | Scotland XI v Army XI | Raeburn Place, Edinburgh | 1949 |
| 75 | GL Willatt | Scotland XI v Army XI | Raeburn Place, Edinburgh | 1949 |
| 63 | AM Zuill | Scotland XI v New Zealand Cricket Council XI | Whitehaugh Oval, Paisley | 1964 |
| 65* | JMC Ford | Scotland XI v Denmark | Raeburn Place, Edinburgh | 1966 |
| 111 | DS Mackintosh | Scotland B v Marylebone Cricket Club Young Professionals | North Inch, Perth | 1971 |
| 66* | DL Bell | Scotland A v Marylebone Cricket Club Young Cricketers | Barclay's Bank Ground, Norbury | 1972 |
| 70 | DBS Brown | Scotland A v Marylebone Cricket Club Young Cricketers | Barclay's Bank Ground, Norbury | 1972 |
| 85 | TW Porteous | Scotland B v British Police | Ferryfield, Edinburgh | 1975 |
| 62 | DF Forrest | Scotland B v Durham | The Tryst, Stenhousemuir | 1976 |
| 96* | STT Wilkinson | Scotland B v Central Lancashire League | The Paddock, Royton | 1980 |
| 58 | ETN Pollock | Scotland B v Central Lancashire League | Nunholm, Dumfries | 1981 |
| 62 | G Lawrence | Scotland B v Durham University | Lochside Park, Forfar | 1984 |
| 56* | NW Burnett | Scotland B v Durham University | The Racecourse, Durham | 1985 |
| 59* | AL Goram | Scotland B v Kingfisher Colts | Nunholm, Dumfries | 1989 |
| 88 | AG Davies | Scotland B v Star Club of India | Titwood, Glasgow | 1993 |
| 65 | DR Lockhart | Scotland B v Durham Second XI | Langwell Crescent, Ashington | 1994 |
| 117 | RA Parsons | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1995 |
| 107 | CV English | Scotland XI v Glamorgan | Sophia Gardens, Cardiff | 2002 |
| 66* | ST Knox | Scotland B v Marylebone Cricket Club | Denis Compton Oval, Shenley | 2004 |
| 97 | JH Stander | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2007 |
| 95 | AJ Crosthwaite | Scotland XI v United Arab Emirates | Glenpark, Greenock | 2007 |
| 70 | SW Dalgleish | Scotland A v Leicestershire Second XI | Leicester Road, Hinckley | 2008 |
| 53* | AJL Baum | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 53* | AD Mathews | Basnahira v Kandurata | R Premadasa Stadium, Colombo | 2013 |
| 75 | Asif Iqbal | United Arab Emirates v Scotland XI | The Ageas Bowl, Southampton | 2015 |
| 92 | TB Sole | Scotland Development XI v Yorkshire Academy | Weetwood Playing Fields, Leeds | 2015 |
| 76 | BJ Horne | Auckland v Scotland | Kerrydale, Robina | 2017/18 |
| 106 | GD Phillips | Auckland v Scotland | Kerrydale, Robina | 2017/18 |