| Inns | HS |
| 485 | 91 | Scotland (1) v Ireland | North Inch, Perth | 1909 |
| 411-6d | 83 | Scotland (1) v Ireland | Raeburn Place, Edinburgh | 1956 |
| 391 | 82 | Scotland (1) v Netherlands | Sportpark Het Schootsveld, Deventer | 2010 |
| 353-7d | 93 | Scotland (1) v Pakistanis | Raeburn Place, Edinburgh | 1954 |
| 346-8d | 89 | Scotland (2) v Warwickshire | Edgbaston, Birmingham | 1961 |
| 325 | 97 | Scotland (1) v Ireland | Glenpark, Greenock | 1932 |
| 324-8 | 94 | Scotland v Ireland | Castle Avenue, Dublin | 2005 |
| 323 | 70 | Scotland (1) v Northamptonshire | Raeburn Place, Edinburgh | 1951 |
| 323-5 | 89 | Scotland v Ireland | Raeburn Place, Edinburgh | 2011 |
| 316 | 99* | Scotland (2) v New Zealanders | Hamilton Crescent, Glasgow | 1965 |
| 316-5d | 92 | Scotland (1) v Worcestershire | Forthill, Dundee | 1982 |
| 316 | 67 | Scotland (2) v Afghanistan | Cambusdoon New Ground, Alloway | 2010 |
| 315 | 99 | Scotland (2) v Ireland | North Inch, Perth | 1950 |
| 315 | 66 | Scotland (1) v Ireland | Myreside, Edinburgh | 1982 |
| 314-7d | 88* | Scotland (1) v Netherlands | Mannofield Park, Aberdeen | 2004 |
| 314 | 93 | Scotland (1) v Ireland | Civil Service Cricket Club, Stormont, Belfast | 2007 |
| 310 | 91 | Scotland (1) v Ireland | College Park, Dublin | 1939 |
| 309 | 83 | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2017 |
| 308 | 72 | Scotland (1) v Sir J Cahn's XI | West Park, West Bridgford | 1939 |
| 307-9 | 74 | Scotland v Ireland | ICC Cricket Academy Ground, Dubai | 2017/18 |
| 306 | 89 | Scotland (2) v Gloucestershire | Raeburn Place, Edinburgh | 1891 |
| 306 | 85 | Scotland v New Zealand | Raeburn Place, Edinburgh | 2022 |
| 304 | 70 | Scotland (1) v Ireland | Raeburn Place, Edinburgh | 1890 |
| 304 | 81 | Scotland (2) v West Indians | Raeburn Place, Edinburgh | 1906 |
| 303-5 | 96 | Scotland v Oman | Al Amerat Cricket Ground, Al Amerat | 2018/19 |
| 299-9 | 90 | Scotland v United Arab Emirates | ICC Cricket Academy Ground, Dubai | 2017/18 |
| 297 | 75 | Scotland (1) v Ireland | Hamilton Crescent, Glasgow | 1922 |
| 296-6d | 74 | Scotland (1) v Ireland | Hamilton Crescent, Glasgow | 1968 |
| 294-7 | 79 | Scotland (2) v Ireland | Hamilton Crescent, Glasgow | 1911 |
| 291 | 67 | Scotland (1) v Lancashire | Old Trafford Practice Ground, Manchester | 1978 |