| 190 | AK McTavish (69) & BR Tod (143*) | Scotland v Ireland | Raeburn Place, Edinburgh | 1936 |
| 144 | TN Gallacher (73) & JM Allan (99*) | Scotland v New Zealanders | Hamilton Crescent, Glasgow | 1965 |
| 129 | J Aitchison (108) & WA Edward (66) | Scotland v Ireland | College Park, Dublin | 1951 |
| 125 | RD Berrington (102) & MA Leask (96*) | Scotland v Nepal | Forthill, Dundee | 2025 |
| 121 | O Henry (74) & AB Russell (48) | Scotland v Indians | Titwood, Glasgow | 1990 |
| 120 | W Nichol (139*) & WA Edward (51) | Scotland v Warwickshire | Edgbaston, Birmingham | 1951 |
| 118 | CJO Smith (93) & KJ Coetzer (133*) | Scotland v Kenya | Sheikh Zayed Stadium, Abu Dhabi | 2004/05 |
| 116 | AK McTavish (109) & T Spowart (66) | Scotland v South Americans | Raeburn Place, Edinburgh | 1932 |
| 116 | CS MacLeod (102) & CD Wallace (52) | Scotland v Hong Kong | Raeburn Place, Edinburgh | 2016 |
| 114 | KJ Coetzer (108*) & MA Leask (47) | Scotland v United Arab Emirates | Choice Moosa Stadium, Pearland | 2022 |
| 113 | JM Allan (65*) & D Barr (62) | Scotland v Warwickshire | Edgbaston, Birmingham | 1967 |
| 113 | O Henry (89) & MJD Allingham (55*) | Scotland v England Amateur XI | Eastwood Gardens, Gateshead | 1991 |
| 113 | PL Mommsen (78) & CD de Lange (55*) | Scotland v Nepal | Cambusdoon New Ground, Alloway | 2015 |
| 112 | CV English (65) & CM Wright (88*) | Scotland v Netherlands | Mannofield Park, Aberdeen | 2004 |
| 105* | JM Allan (40*) & D Barr (66*) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1964 |
| 103 | W Nichol (50) & WA Edward (64) | Scotland v Yorkshire | Raeburn Place, Edinburgh | 1950 |
| 103 | A Steele (49) & F Robertson (51) | Scotland v Ireland | Observatory Lane, Rathmines, Dublin | 1979 |
| 101 | J Brown (63) & KM Hardie (39) | Scotland v Warwickshire | Edgbaston, Birmingham | 1973 |
| 99 | J Kerr (74) & CS Paterson (49) | Scotland v Ireland | Observatory Lane, Rathmines, Dublin | 1914 |
| 99 | RD Berrington (110) & SJS Smith (54) | Scotland v United Arab Emirates | Sharjah Cricket Association Stadium, Sharjah | 2011/12 |
| 98 | BL Peel (65) & HD Keigwin (41) | Scotland v South Africans | Raeburn Place, Edinburgh | 1907 |
| 95 | CS MacLeod (58) & MA Leask (59) | Scotland v Ireland | ICC Cricket Academy Ground, Dubai | 2017/18 |
| 94 | JR Laing (127*) & DM Peden (45) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1976 |
| 93 | RD Berrington (59) & RML Taylor (52) | Scotland v Netherlands | Sportpark Westvliet, Voorburg | 2015 |
| 92 | JD Martin (88) & AK McTavish (69) | Scotland v Ireland | College Park, Dublin | 1929 |
| 92 | CJ Richards (88*) & IA Moran (42) | Scotland v Worcestershire | Raeburn Place, Edinburgh | 2006 |
| 92 | MH Cross (53) & MA Leask (85) | Scotland v New Zealand | Raeburn Place, Edinburgh | 2022 |
| 92 | CS MacLeod (133*) & MA Leask (41) | Scotland v United States of America | Mannofield Park, Aberdeen | 2022 |
| 91 | RD Berrington (129) & MA Leask (58) | Scotland v Papua New Guinea | Amini Park, Port Moresby | 2017/18 |
| 89* | WH Thorburn (46*) & WF Turnbull (41*) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1911 |
| 89 | TB Racionzer (57) & JM Allan (35) | Scotland v Ireland | Sydney Parade, Dublin | 1965 |
| 89 | G Salmond (74) & MJD Allingham (32) | Scotland v Wales | St Helen's, Swansea | 1996 |
| 86 | RR Watson (70) & RM Haq (35) | Scotland v Derbyshire | County Ground, Derby | 2003 |
| 86 | NFI McCallum (121*) & CM Wright (19) | Scotland v Ireland | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 84 | MJ Smith (79) & DL Snodgrass (49) | Scotland v Ireland | Lodge Road, Coleraine | 1987 |
| 84 | IM Stanger (37*) & JG Williamson (48) | Scotland v Ireland | Sportpark Craeyenhout, The Hague | 1998 |
| 84 | RD Berrington (101*) & JH Davey (40) | Scotland v Ireland | The Village, Malahide, Dublin | 2014 |
| 83 | CD Wallace (58) & MA Leask (59*) | Scotland v Zimbabwe | Raeburn Place, Edinburgh | 2017 |
| 82 | G Salmond (79) & MJD Allingham (28) | Scotland v Denmark | Raeburn Place, Edinburgh | 1997 |
| 80 | PL Mommsen (48) & RM Haq (53*) | Scotland v Hampshire | The Ageas Bowl, Southampton | 2012 |