| 7-21 | CAA Cassell | Scotland v Oman | Forthill, Dundee | 2024 |
| 6-28 | JH Davey | Scotland v Afghanistan | Sheikh Zayed Stadium, Abu Dhabi | 2014/15 |
| 5-9 | JH Davey | Scotland v Afghanistan | Cambusdoon New Ground, Alloway | 2010 |
| 5-22 | JAR Blain | Scotland v Netherlands | Castle Avenue, Dublin | 2008 |
| 5-33 | SM Sharif | Scotland v Zimbabwe | Queens Sports Club, Bulawayo | 2017/18 |
| 5-33 | MRJ Watt | Scotland v United Arab Emirates | Mannofield Park, Aberdeen | 2022 |
| 5-34 | B McMullen | Scotland v Ireland | Queens Sports Club, Bulawayo | 2023 |
| 5-35 | SM Sharif | Scotland v Namibia | Titwood, Glasgow | 2022 |
| 5-38 | H Tahir | Scotland v Oman | Mannofield Park, Aberdeen | 2019 |
| 5-43 | AC Evans | Scotland v Netherlands | Hazelaarweg, Rotterdam | 2021 |
| 5-52 | GT Main | Scotland v Papua New Guinea | Dubai Sports City Stadium, Dubai | 2022 |
| 5-53 | CN Greaves | Scotland v Oman | Bulawayo Athletic Club, Bulawayo | 2023 |
| 5-54 | RM Haq | Scotland v Ireland | The Village, Malahide, Dublin | 2014 |
| 5-60 | CD de Lange | Scotland v Zimbabwe | Raeburn Place, Edinburgh | 2017 |
| 5-73 | G Goudie | Scotland v Australia | Raeburn Place, Edinburgh | 2009 |
| 4-15 | TB Sole | Scotland v Hong Kong | Bulawayo Athletic Club, Bulawayo | 2017/18 |
| 4-20 | SM Sharif | Scotland v United Arab Emirates | Bulawayo Athletic Club, Bulawayo | 2023 |
| 4-22 | I Wardlaw | Scotland v Afghanistan | Sheikh Zayed Stadium, Abu Dhabi | 2014/15 |
| 4-23 | JJ Davidson | Scotland v Oman | Forthill, Dundee | 2024 |
| 4-24 | MA Leask | Scotland v Namibia | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 4-25 | JD Nel | Scotland v Ireland | Mannofield Park, Aberdeen | 2008 |
| 4-26 | GT Main | Scotland v Papua New Guinea | Dubai Sports City Stadium, Dubai | 2022 |
| 4-26 | H Tahir | Scotland v Nepal | Titwood, Glasgow | 2022 |
| 4-27 | SM Sharif | Scotland v Netherlands | Mannofield Park, Aberdeen | 2011 |
| 4-27 | CB Sole | Scotland v United Arab Emirates | Choice Moosa Stadium, Pearland | 2022 |
| 4-28 | RM Haq | Scotland v West Indies | Castle Avenue, Dublin | 2007 |
| 4-28 | CB Sole | Scotland v Hong Kong | Raeburn Place, Edinburgh | 2016 |
| 4-29 | CM Wright | Scotland v Canada | Mombasa Sports Club Ground, Mombasa | 2006/07 |
| 4-30 | MRJ Watt | Scotland v United Arab Emirates | Mannofield Park, Aberdeen | 2022 |
| 4-32 | CN Greaves | Scotland v Sri Lanka | Queens Sports Club, Bulawayo | 2023 |
| 4-32 | BJ Currie | Scotland v United States of America | Grand Prairie Stadium, Grand Prairie | 2024/25 |
| 4-33 | MA Parker | Scotland v Kenya | Hazelaarweg, Rotterdam | 2010 |
| 4-33 | RM Haq | Scotland v Netherlands | Mannofield Park, Aberdeen | 2011 |
| 4-37 | JAR Blain | Scotland v Bangladesh | Raeburn Place, Edinburgh | 1999 |
| 4-37 | MA Leask | Scotland v Zimbabwe | Queens Sports Club, Bulawayo | 2017/18 |
| 4-37 | H Tahir | Scotland v Papua New Guinea | Mannofield Park, Aberdeen | 2019 |
| 4-38 | SM Sharif | Scotland v Papua New Guinea | Dubai Sports City Stadium, Dubai | 2017/18 |
| 4-40 | RD Berrington | Scotland v Afghanistan | University Oval, Dunedin | 2014/15 |
| 4-40 | MA Leask | Scotland v Namibia | Forthill, Dundee | 2024 |
| 4-40 | JA Jarvis | Scotland v United States of America | Grand Prairie Stadium, Grand Prairie | 2024/25 |
| 4-41 | GD Drummond | Scotland v Canada | Mannofield Park, Aberdeen | 2009 |
| 4-41 | AC Evans | Scotland v Hong Kong | Mission Road Ground, Hong Kong | 2015/16 |
| 4-41 | AC Evans | Scotland v United Arab Emirates | Raeburn Place, Edinburgh | 2016 |
| 4-41 | MRJ Watt | Scotland v Namibia | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 4-42 | MRJ Watt | Scotland v United States of America | Sharjah Cricket Association Stadium, Sharjah | 2019/20 |
| 4-43 | I Wardlaw | Scotland v Kenya | Mannofield Park, Aberdeen | 2013 |
| 4-68 | JH Davey | Scotland v England | Hagley Oval, Christchurch | 2014/15 |
| 4-68 | CB Sole | Scotland v United Arab Emirates | Queens Sports Club, Bulawayo | 2017/18 |