| 108 | HW Taylor (125) & EA van der Merwe (35*) | South Africans v Scotland | North Inch, Perth | 1929 |
| 89 | AP Arnold (61) & S Starkie (35*) | Northamptonshire v Scotland | Raeburn Place, Edinburgh | 1951 |
| 83 | SJS Smith (29*) & GD Drummond (52) | Scotland v Canada | Mannofield Park, Aberdeen | 2009 |
| 78 | TA Bowie (66) & GK Chalmers (40*) | Scotland v Nottinghamshire | Raeburn Place, Edinburgh | 1908 |
| 73 | [unknown] & [unknown] | New Zealanders v Scotland | Hamilton Crescent, Glasgow | 1949 |
| 67 | J Kerr (64*) & WL Fraser (44) | Scotland v Ireland | Raeburn Place, Edinburgh | 1913 |
| 62* | RO Collinge (63*) & SL Boock (14*) | New Zealanders v Scotland | Forthill, Dundee | 1978 |
| 61 | HF Mulla (51) & Syed Hussain (14) | Indians v Scotland | Mossilee, Galashiels | 1911 |
| 61 | NE Thompson (38) & M Halliday (29*) | Ireland v Scotland | Nunholm, Dumfries | 1988 |
| 52 | SC Corlett (23) & J McBrine (27*) | Ireland v Scotland | Titwood, Glasgow | 1986 |
| 51 | J Brown (38) & KM Hardie (19*) | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1967 |
| 51 | OD Colhoun (9*) & DE Goodwin (39) | Ireland v Scotland | Glenpark, Greenock | 1972 |
| 49 | PR Umrigar (153*) & Surendranath (9) | Indians v Scotland | Whitehaugh Oval, Paisley | 1959 |
| 45 | RI Gill (37) & JW Hill (14*) | Ireland v Scotland | North Inch, Perth | 1950 |
| 43 | GF Macnamara (30) & GWFB Kelly (25) | Ireland v Scotland | Raeburn Place, Edinburgh | 1913 |
| 42 | GAA Duffy (55*) & KW Hope (13) | Ireland v Scotland | Whitehaugh Oval, Paisley | 1960 |
| 41 | Samiullah Shenwari (51*) & Izatullah Dawlatzai (18) | Afghanistan v Scotland | New Williamfield, Stirling | 2015 |
| 40 | WH Thorburn (90*) & R Gardiner (28) | Scotland v Ireland | North Inch, Perth | 1909 |
| 39 | W Nichol (56) & SJ Thomson (15) | Scotland v Ireland | Glenpark, Greenock | 1946 |
| 39 | MA Parker (42) & GD Drummond (15) | Scotland v Afghanistan | Cambusdoon New Ground, Alloway | 2010 |
| 36 | TD Watt (21) & RS Cranston (31) | Scotland v Surrey | Hamilton Crescent, Glasgow | 1923 |
| 35 | JG Heaslip (17) & BJ Ward (17) | Ireland v Scotland | Raeburn Place, Edinburgh | 1920 |