| 240 | RR Watson (154) & NFI McCallum (181) | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 198 | GJ Bailey (123*) & RD Berrington (82) | Scotland v Warwickshire | Edgbaston, Birmingham | 2010 |
| 177 | RR Watson (167) & CJO Smith (70) | Scotland v Namibia | Mannofield Park, Aberdeen | 2006 |
| 167 | RS Dravid (69) & JC Kent (115*) | Scotland v Sussex | County Ground, Hove | 2003 |
| 167* | RD Berrington (114*) & HG Munsey (79*) | Scotland v Papua New Guinea | Dubai Sports City Stadium, Dubai | 2022 |
| 165 | G Salmond (181) & JG Williamson (55) | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 162 | MW Machan (114) & PL Mommsen (63*) | Scotland v Kenya | Mannofield Park, Aberdeen | 2013 |
| 160 | DF Watts (171*) & NFI McCallum (52) | Scotland v Denmark | New Anniesland, Glasgow | 2006 |
| 153* | DF Watts (81*) & CJO Smith (86*) | Scotland v Canada | Upritchard Park, Bangor | 2005 |
| 145 | CV English (75*) & GM Hamilton (59) | Scotland v Bermuda | The Vineyard, Dublin | 2005 |
| 143 | IL Philip (234) & O Henry (102*) | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 142* | GN Reifer (153*) & J Everett (30*) | Scotland v Transvaal University | Eben Cuyler Park, Johannesburg | 1991/92 |
| 141 | KJ Coetzer (156) & PL Mommsen (39) | Scotland v Bangladesh | Saxton Oval, Nelson | 2014/15 |
| 141 | RD Berrington (72*) & HG Munsey (96) | Scotland v Oman | Al Amerat Cricket Ground, Al Amerat | 2018/19 |
| 137 | B McMullen (106) & RD Berrington (64) | Scotland v Netherlands | Queens Sports Club, Bulawayo | 2023 |
| 125 | RHE Chisholm (83) & J Aitchison (78*) | Scotland v Middlesex | Raeburn Place, Edinburgh | 1962 |
| 124 | RD Berrington (67) & NFI McCallum (89*) | Scotland v Canada | VRA Ground, Amstelveen | 2010 |
| 119 | RS Weir (65) & ABM Ker (58) | Scotland v Ireland | Myreside, Edinburgh | 1982 |
| 118 | DF Watts (146) & RR Watson (57) | Scotland v Kenya | Sheikh Zayed Stadium, Abu Dhabi | 2004/05 |
| 118 | GM Hamilton (115) & RR Watson (56) | Scotland v Canada | Sharjah Cricket Association Stadium, Sharjah | 2004/05 |
| 118 | CS MacLeod (175) & FRJ Coleman (40) | Scotland v Canada | Hagley Oval, Christchurch | 2013/14 |
| 118 | PL Mommsen (60) & FRJ Coleman (70) | Scotland v Sri Lanka | Blundstone Arena, Hobart | 2014/15 |
| 116 | RD Berrington (107*) & HG Munsey (51) | Scotland v United States of America | Choice Moosa Stadium, Pearland | 2022 |
| 114 | G Salmond (118) & AB Russell (33) | Scotland v Ireland | Forthill, Dundee | 1992 |
| 113 | G Salmond (95) & AB Russell (29*) | Scotland v Ireland | Forthill, Dundee | 1992 |
| 113 | GM Hamilton (56) & NFI McCallum (101*) | Scotland v Uganda | Walter Milton Oval, University of Witwatersrand, Johannesburg | 2008/09 |
| 113 | CS MacLeod (77) & MH Cross (85) | Scotland v United Arab Emirates | Mannofield Park, Aberdeen | 2022 |
| 107 | CS MacLeod (140*) & HG Munsey (55) | Scotland v England | Raeburn Place, Edinburgh | 2018 |
| 105 | KJ Coetzer (68) & NFI McCallum (103) | Scotland v Namibia | LC de Villiers Oval, Pretoria | 2008/09 |
| 104 | JM Allan (44) & FA Jones (52) | Scotland v Australians | Raeburn Place, Edinburgh | 1961 |
| 103 | RS Dravid (81) & JC Kent (78*) | Scotland v Hampshire | The Rose Bowl, Southampton | 2003 |
| 103 | DF Watts (83) & CJO Smith (38) | Scotland v Bermuda | National Stadium, Hamilton | 2008 |
| 102 | MQ Sheikh (108) & RD Berrington (80) | Scotland v Kenya | Gymkhana Club Ground, Nairobi | 2009/10 |
| 101* | G Salmond (56*) & AB Russell (38*) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1990 |
| 101 | RA Parsons (48) & G Salmond (43) | Scotland v Canada | Armour Heights, Toronto | 2001 |
| 100 | MJ Smith (61) & GM Hamilton (91*) | Scotland v Durham | Riverside Ground, Chester-le-Street | 1999 |
| 100 | RS Dravid (120*) & JC Kent (48) | Scotland v Somerset | County Ground, Taunton | 2003 |