| 1 | 234 | IL Philip | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 2 | 175 | CS MacLeod | Scotland v Canada | Hagley Oval, Christchurch | 2013/14 |
| 3 | 190* | J Aitchison | Scotland v Ireland | College Park, Dublin | 1959 |
| 4 | 181 | G Salmond | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 5 | 181 | NFI McCallum | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 6 | 139* | W Nichol | Scotland v Warwickshire | Edgbaston, Birmingham | 1951 |
| 7 | 143* | BR Tod | Scotland v Ireland | Raeburn Place, Edinburgh | 1936 |
| 8 | 110 | CT Mannes | Scotland v Gentlemen of Philadelphia | Raeburn Place, Edinburgh | 1889 |
| 9 | 113* | GF Goddard | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1973 |
| 10 | 55 | J Brown | Scotland v Ireland | College Park, Dublin | 1955 |
| 11 | 44* | G Goudie | Scotland v Netherlands | Sportpark Het Schootsveld, Deventer | 2010 |
| 12 | 0* | JH Broadley | Scotland v Sussex | Hamilton Crescent, Glasgow | 1903 |