| Inns | HS |
| 234-8 | 48 | Scotland v Zimbabwe | Queens Sports Club, Bulawayo | 2023 |
| 221 | 47 | Scotland v Namibia | Tribhuvan University International Cricket Ground, Kirtipur | 2022/23 |
| 210 | 31 | Scotland v Afghanistan | University Oval, Dunedin | 2014/15 |
| 210 | 47 | Scotland v Zimbabwe | Queens Sports Club, Bulawayo | 2017/18 |
| 209-8 | 45 | Scotland v Canada | Mombasa Sports Club Ground, Mombasa | 2006/07 |
| 206 | 44 | Scotland v Afghanistan | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 203-9 | 44 | Scotland v India | Titwood, Glasgow | 2007 |
| 199 | 43 | Scotland v United Arab Emirates | VRA Ground, Amstelveen | 2025 |
| 197 | 36 | Scotland v Canada | Dubai Sports City Stadium, Dubai | 2023/24 |
| 186-8 | 45* | Scotland v South Africa | Warner Park, Basseterre | 2006/07 |
| 181-7 | 34 | Scotland v Australia | County Ground, New Road, Worcester | 1999 |
| 171 | 30 | Scotland v United Arab Emirates | Choice Moosa Stadium, Pearland | 2022 |
| 165 | 39 | Scotland v Ireland | Civil Service Cricket Club, Stormont, Belfast | 2013 |
| 162 | 39 | Scotland v Australia | Raeburn Place, Edinburgh | 2013 |
| 156 | 38 | Scotland v Australia | Raeburn Place, Edinburgh | 2009 |
| 155 | 31 | Scotland v Ireland | Cambusdoon New Ground, Alloway | 2006 |
| 155 | 30 | Scotland v Kenya | Gymkhana Club Ground, Nairobi | 2006/07 |
| 154 | 34 | Scotland v Nepal | Grand Prairie Stadium, Grand Prairie | 2024/25 |
| 153 | 30 | Scotland v Bangladesh | Bir Shrestha Shahid Ruhul Amin Stadium, Chittagong | 2006/07 |
| 152-7 | 40 | Scotland v West Indies | Castle Avenue, Dublin | 2007 |
| 149-8 | 41 | Scotland v Netherlands | Hazelaarweg, Rotterdam | 2021 |
| 143-7 | 43 | Scotland v Nepal | Wanderers Cricket Ground, Windhoek | 2022/23 |
| 142-8 | 46 | Scotland v Afghanistan | Hazelaarweg, Rotterdam | 2010 |
| 138-6 | 47 | Scotland v Netherlands | Cambusdoon New Ground, Alloway | 2006 |
| 138 | 22* | Scotland v Kenya | Mombasa Sports Club Ground, Mombasa | 2006/07 |
| 136 | 26 | Scotland v Netherlands | Warner Park, Basseterre | 2006/07 |
| 135 | 32 | Scotland v Pakistan | Raeburn Place, Edinburgh | 2013 |
| 133-9 | 42 | Scotland v England | Mannofield Park, Aberdeen | 2014 |
| 132 | 29 | Scotland v Bangladesh | Shere Bangla National Stadium, Mirpur | 2006/07 |
| 132 | 33 | Scotland v Afghanistan | Raeburn Place, Edinburgh | 2016 |