| 5-3 | MJ McColl | Scotland Women v France Women | La Manga Club Bottom Ground, La Manga | 2021 |
| 5-17 | RE Slater | Scotland Women v Uganda Women | Tolerance Oval, Abu Dhabi | 2024 |
| 5-20 | K Anderson | Scotland Women v Lancashire Women | Highfield, Broughton | 2011 |
| 5-34 | A Aitken | Scotland Women v Worcestershire Women | Cherry Hill Road, Barnt Green | 2015 |
| 5-41 | HRA Rainey | Scotland Women v Ireland Women | Desert Springs, Almeria | 2023/24 |
| 5-61 | K Anderson | Scotland Women v Pakistan Women | Van der Stel Cricket Club Ground, Stellenbosch | 2007/08 |
| 4-1 | K Anderson | Scotland Women v Cheshire Women | Akeman Street, Chesterton | 2016 |
| 4-5 | KE Bryce | Scotland Women v Devon Women | Whitehorn Lane, Letchworth | 2016 |
| 4-7 | LI Wilkinson | Scotland Women v Worcestershire Women | Spytty Park, Newport | 2017 |
| 4-8 | KE Bryce | Scotland Women v Ireland Women | Sheikh Zayed Stadium, Abu Dhabi | 2024 |
| 4-10 | RV Scholes | Scotland Women v Thailand Women | Sportpark Maarschalkerweerd, Utrecht | 2018 |
| 4-13 | K Anderson | Scotland Women v Northamptonshire Women | Redwell Road, Wellingborough | 2012 |
| 4-13 | K Anderson | Scotland Women v Oxfordshire Women | Akeman Street, Chesterton | 2016 |
| 4-14 | NM Sheikh | Scotland Women v Netherlands Women | VRA Ground, Amstelveen | 2024 |
| 4-15 | K White | Scotland Women v Hampshire Women | The Trojans Club, Eastleigh | 2009 |
| 4-15 | LI Wilkinson | Scotland Women v Gloucestershire Women | Englands, Poulton | 2014 |
| 4-15 | K Anderson | Scotland Women v Oxfordshire Women | Akeman Street, Chesterton | 2016 |
| 4-17 | KE Bryce | Scotland Women v United States of America Women | Tolerance Oval, Abu Dhabi | 2024 |
| 4-18 | K Anderson | Scotland Women v Durham Women | Bunker Hill, Philadelphia | 2001 |
| 4-18 | A Aitken | Scotland Women v Hampshire Women | The Trojans Club, Eastleigh | 2009 |
| 4-19 | FE Urquhart | Scotland Women v Worcestershire Women | Seth Somers Park, Halesowen | 2009 |
| 4-19 | KJG Fraser | Scotland Women v Malaysia Women | Kinrara Academy Oval, Kuala Lumpur | 2021/22 |
| 4-20 | R Sangsoma | Thailand Women v Scotland Women | Civil Service Cricket Club Ground, Phoenix Park, Dublin | 2013 |
| 4-24 | SM Horley | Scotland Women v Papua New Guinea Women | Sportpark Maarschalkerweerd, Utrecht | 2024 |
| 4-25 | C McLaughlin | Scotland Women v Durham Women | New Field, Edinburgh | 2000 |
| 4-25 | FE Campbell | Scotland Women v Japan Women | Sportpark Klein Zwitserland, The Hague | 2003 |
| 4-29 | KL Gordon | Scotland Women v Pakistan Women | Colombo Cricket Club Ground, Colombo | 2016/17 |
| 4-30 | A Aitken | Scotland Women v Cumbria Women | New Williamfield, Stirling | 2008 |
| 4-30 | AM Maqsood | Scotland Women v United States of America Women | ICC Cricket Academy Ground, Dubai | 2024 |
| 4-33 | LI Wilkinson | Scotland Women v Hampshire Women | Southern Gardens, Totton | 2010 |
| 4-33 | K Anderson | Scotland Women v Netherlands Women | Loxley Close, Wellesbourne | 2014 |
| 4-37 | AM Maqsood | Scotland Women v Papua New Guinea Women | Sportpark Maarschalkerweerd, Utrecht | 2024 |
| 4-38 | VSC Maxwell | Scotland Women v Pakistan Women | Donkere Laan, Bloemendaal | 2003 |
| 4-40 | A Aitken | Scotland Women v Hertfordshire Women | London Road, Tring | 2014 |