| 156 | HG Munsey (77) & MA Leask (91) | Scotland v Ireland | Queens Sports Club, Bulawayo | 2017/18 |
| 145 | DE Budge (151) & R Henry (67) | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2018 |
| 128 | GI Maiden (58*) & JD Love (74) | Scotland B v Yorkshire Academy | The Playing Field, Stamford Bridge | 1999 |
| 91 | SJ Chalmers (63*) & MA Parker (44) | Scotland A v England Under-18s | Titwood, Glasgow | 2009 |
| 77 | JC Kent (83*) & JE Brinkley (30) | Scotland XI v Durham University Centre of Cricketing Excellence Second XI | Raeburn Place, Edinburgh | 2003 |
| 76 | AB Russell (42) & GP Cooke (39*) | Scotland XI v AM Ferreira's XI | Centurion Park, Verwoerdburg | 1991/92 |
| 74* | MM English (37*) & MRJ Watt (37*) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2016 |
| 72 | G Salmond (120*) & MA Mudie (19) | Scotland B v Yorkshire Second XI | Park Avenue Cricket Ground, Bradford | 1997 |
| 72* | A Bee (39*) & S Gourlay (27*) | Scotland XI v Bangladeshis | Glenpark, Greenock | 1998 |
| 68 | JH Stander (97) & RM Haq (35) | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2007 |
| 67 | RM Haq (66) & SJS Smith (38) | Scotland A v Warwickshire Second XI | Rugby School Ground, Rugby | 2010 |
| 66 | JSD Moffat (71*) & AM Burgess (34) | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1996 |
| 66 | NFI McCallum (70) & CM Wright (47*) | Scotland v Kenya | Willowmoore Park B Field, Benoni | 2008/09 |
| 66 | HG Munsey (66) & MRJ Watt (21) | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2016 |
| 65* | CS MacLeod (59) & RM Haq (36*) | Scotland v Surrey | Raeburn Place, Edinburgh | 2013 |
| 65 | SP Patil (100) & Fayyaz Ahmed (30) | United Arab Emirates v Scotland XI | The Ageas Bowl, Southampton | 2015 |
| 65 | MA Leask (92*) & CJ Tear (29) | Scotland v United Arab Emirates Falcons | Dubai Sports City Stadium, Dubai | 2023/24 |
| 63 | MJD Allingham (39*) & IM Stanger (41) | Scotland XI v Durham | Riverside Ground, Chester-le-Street | 1996 |
| 63 | HG Munsey (43*) & SM Sharif (27) | Scotland v Auckland | Kerrydale, Robina | 2017/18 |
| 61 | MJ Petrie (24) & CG Burnett (32) | Scotland A v Ireland A | Bothwell Castle, Uddingston | 2012 |
| 60 | RO Hussain (83) & UA Mohammad (35) | Scotland Under-23s v Ireland Under-23s | The Vineyard, Dublin | 2006 |
| 57 | MH Cross (18) & MA Leask (62) | Scotland XI v United Arab Emirates | The Ageas Bowl, Southampton | 2015 |
| 56 | O Henry (84) & JW Govan (17) | Scotland B v Leicestershire Second XI | Grace Road, Leicester | 1988 |
| 55 | RO Hussain (83) & SJS Smith (25) | Scotland A v Durham Second XI | Derwenthaugh Park, Swalwell | 2007 |
| 55 | TB Sole (39) & MRJ Watt (24) | Scotland A v Durham Second XI | Roseworth Terrace, Gosforth | 2020 |
| 54 | DF Watts (67) & GI Maiden (31) | Scotland XI v Derbyshire Second XI | Town Ground, Heanor | 2001 |
| 54 | SA Murray (23) & GI Maiden (47) | Scotland B v Marylebone Cricket Club | Denis Compton Oval, Shenley | 2004 |
| 54 | RD Berrington (54) & MQ Sheikh (53*) | Scotland A v Nottinghamshire Second XI | Nottinghamshire Sports Ground, Nottingham | 2008 |
| 52 | SJ Chalmers (24) & MJ Petrie (39) | Scotland A v Jersey | Farmers Cricket Club Ground, St Martin | 2010 |
| 49 | MJ Smith (37) & NW Burnett (35) | Scotland B v Durham University | The Racecourse, Durham | 1987 |
| 49 | RM Haq (47*) & MM Iqbal (15) | Scotland A v Netherlands A | Hazelaarweg, Rotterdam | 2008 |
| 49 | MM Iqbal (55*) & SJS Smith (17) | Scotland A v Ireland A | VRA Ground, Amstelveen | 2008 |
| 49 | NFI McCallum (33) & CM Wright (38) | Scotland v Gauteng XI | LC de Villiers Oval, Pretoria | 2008/09 |
| 49 | CD Wallace (29) & RT Lyons (10) | Scotland A v Bath | North Parade, Bath | 2018 |
| 48* | MJ Smith (65*) & JD Love (24*) | Scotland B v Durham University | The Racecourse, Durham | 1994 |
| 47* | RO Hussain (124*) & GC Holmes (21*) | Scotland A v Lancashire Second XI | Meikleriggs, Paisley | 2006 |
| 47 | SJ Chalmers (32) & MA Parker (74) | Scotland A v Leicestershire Second XI | Bath Grounds, Ashby-de-la-Zouch | 2010 |
| 47 | MA Leask (80) & MRJ Watt (8) | Scotland A v Ireland Wolves | Forthill, Dundee | 2018 |
| 46 | TW Porteous (85) & RG Rodger (9) | Scotland B v British Police | Ferryfield, Edinburgh | 1975 |
| 46 | IM Stanger (43) & RE More (19) | Scotland XI v Northamptonshire | County Ground, Northampton | 2002 |
| 45 | SJS Smith (30) & GD Drummond (30) | Scotland A v Netherlands A | Upritchard Park, Bangor | 2003 |
| 45* | DR Brown (54*) & JAR Blain (22*) | Scotland XI v Barbados | Three Ws Oval, Cave Hill | 2005/06 |
| 45 | [unknown] & [unknown] | Scotland XI v United Arab Emirates | Dubai Sports City Stadium, Dubai | 2010/11 |
| 45 | CD Wallace (94) & JR Edwards (10*) | Scotland A v Northamptonshire Second XI | West Lodge Park, Desborough | 2012 |