| 1-156 | AC Evans | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2016 |
| 1-138 | GT Main | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2016 |
| 3-137 | JW Govan | Scotland B v Durham Second XI | Grangefield Road, Stockton-on-Tees | 1995 |
| 4-134 | RM Haq | Scotland A v Durham Academy | Titwood, Glasgow | 2006 |
| 5-124 | AN Hunter | Scotland v Australians | Raeburn Place, Edinburgh | 1902 |
| 3-115 | WE Benskin | Scotland v Australian Imperial Forces | Hamilton Crescent, Glasgow | 1919 |
| 3-114 | I Wardlaw | Scotland A v Yorkshire Second XI | North Marine Road, Scarborough | 2014 |
| 0-108 | D Ormiston | Scotland B v Nottinghamshire Second XI | Nottingham High School Ground, Nottingham | 1984 |
| 2-105 | SD Weeraratna | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2010 |
| 2-105 | JD Nel | Scotland A v Warwickshire Second XI | Edgbaston, Birmingham | 2013 |
| 6-104 | H Tahir | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2018 |
| 0-102 | Muzaffar Mahmood | Scotland B v Nottinghamshire Second XI | Trent Bridge, Nottingham | 1990 |
| 1-99 | MA Mudie | Scotland B v Durham Second XI | Grangefield Road, Stockton-on-Tees | 1995 |
| 1-99 | RR Watson | Scotland B v Marylebone Cricket Club | Denis Compton Oval, Shenley | 2004 |
| 2-99 | G Goudie | Scotland A v Yorkshire Second XI | Abbeydale Park, Sheffield | 2008 |
| 4-98 | GC Holmes | Scotland A v Marylebone Cricket Club | Titwood, Glasgow | 2006 |
| 2-97 | G Goudie | Scotland A v Nottinghamshire Second XI | Nottinghamshire Sports Ground, Nottingham | 2008 |
| 2-96 | CV English | Scotland B v Marylebone Cricket Club | Titwood, Glasgow | 2003 |
| 8-96 | RJH Lambert | Scotland XI v Dublin University | College Park, Dublin | 1898 |
| 0-95 | SD Weeraratna | Scotland A v Marylebone Cricket Club | Titwood, Glasgow | 2006 |
| 0-95 | AC Evans | Scotland A v Cavaliers | Bothwell Castle, Uddingston | 2011 |
| 2-94 | HJB Preston | Scotland XI v Australians | Hamilton Crescent, Glasgow | 1930 |
| 3-94 | G Pepall | Scotland v Australians | Raeburn Place, Edinburgh | 1902 |
| 1-93 | KA Stott | Scotland B v Durham Second XI | Langwell Crescent, Ashington | 1994 |
| 1-93 | RT Lyons | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2010 |
| 3-93 | RT Lyons | Scotland A v Marylebone Cricket Club | Cambusdoon New Ground, Alloway | 2009 |
| 3-93 | Amjad Javed | United Arab Emirates v Scotland XI | The Ageas Bowl, Southampton | 2015 |
| 1-92 | MA Leask | Scotland A v Durham Second XI | Hornby Park, Seaton Carew | 2015 |
| 4-92 | Z Bashir | Scotland XI v United Arab Emirates | Glenpark, Greenock | 2007 |
| 2-91 | UA Mohammad | Scotland A v Yorkshire Second XI | The Playing Field, Stamford Bridge | 2007 |
| 2-91 | MM Iqbal | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2014 |