| 8-48 | KM Hardie | Scotland XI v Denmark | Raeburn Place, Edinburgh | 1966 |
| 8-96 | RJH Lambert | Scotland XI v Dublin University | College Park, Dublin | 1898 |
| 7-20 | GT McKiddie | Scotland B v British Police | Ferryfield, Edinburgh | 1975 |
| 6-15 | GD Drummond | Scotland Academy v Guernsey | Raeburn Place, Edinburgh | 2005 |
| 6-18 | JE Laidlay | Scotland XI v Yorkshire | Raeburn Place, Edinburgh | 1878 |
| 6-18 | RA Hollingdale | Scotland XI v Combined Services XI | Philiphaugh, Selkirk | 1944 |
| 6-25 | KM Hardie | Scotland v Ireland | Ormeau, Belfast | 1967 |
| 6-37 | O Henry | Scotland B v Cumberland B | Tynefield Park, Penrith | 1987 |
| 6-40 | O Henry | Scotland B v Durham University | The Racecourse, Durham | 1987 |
| 6-41 | AWJ Stevenson | Scotland B v Nottinghamshire Second XI | Nottingham High School Ground, Nottingham | 1984 |
| 6-43 | KLP Sheridan | Scotland B v Durham University | The Racecourse, Durham | 1995 |
| 6-44 | DN de Neef | Scotland B v Durham University | Nunholm, Dumfries | 1983 |
| 6-59 | W Morton | Scotland B v Durham University | The Racecourse, Durham | 1990 |
| 6-104 | H Tahir | Scotland A v Durham Second XI | Emirates Riverside, Chester-le-Street | 2018 |
| 5-5 | UA Mohammad | Scotland Under-23s v Denmark Under-23s | Sportpark Het Schootsveld 2, Deventer | 2005 |
| 5-19 | AM Tennant | Scotland XI v Ireland | Observatory Lane, Rathmines, Dublin | 1995 |
| 5-22 | C Gosain | Scotland Development XI v Durham Academy | Myreside, Edinburgh | 2013 |
| 5-22 | JH Davey | Scotland XI v Dolphins Premier League All Stars | Hollywoodbets Kingsmead, Durban | 2019/20 |
| 5-23 | CC MacKellar | Scotland B v Durham University | The Racecourse, Durham | 2000 |
| 5-24 | AC Evans | Scotland A v Ireland Wolves | Forthill, Dundee | 2018 |
| 5-25 | JG Williamson | Scotland B v Durham University | The Racecourse, Durham | 1989 |
| 5-25 | MS Richardson | Scotland XI v Manicaland Select XI | Mutare Sports Club, Mutare | 1993/94 |
| 5-25 | SM Sharif | Scotland v Ragama Cricket Club | Nondescripts Cricket Club Ground, Colombo | 2013/14 |
| 5-29 | CG Burnett | Scotland A v Leicestershire Second XI | Ratcliffe College, Cossington | 2013 |
| 5-30 | GE Gardner | Scotland B v Yorkshire Academy | Park Avenue Cricket Ground, Bradford | 1995 |
| 5-33 | AC Evans | Scotland A v Gloucestershire Second XI | North Parade, Bath | 2017 |
| 5-35 | GE Robinson | Scotland XI v Yorkshire | Raeburn Place, Edinburgh | 1888 |
| 5-35 | JT Hainsworth | Scotland XI v Dublin University | College Park, Dublin | 1898 |
| 5-36 | BTJ Wheal | Scotland XI v Marylebone Cricket Club | Titwood, Glasgow | 2015 |
| 5-37 | WA McPate | Scotland B v Scottish Cricket Union President's XI | Hamilton Crescent, Glasgow | 1982 |
| 5-37 | CC MacKellar | Scotland B v Yorkshire Academy | The Playing Field, Stamford Bridge | 1999 |
| 5-37 | RM Haq | Scotland v Barbados XI | Three Ws Oval, Cave Hill | 2006/07 |
| 5-42 | CT McKnight | Scotland B v Durham University | The Racecourse, Durham | 1990 |
| 5-43 | SM Sharif | Scotland XI v United Arab Emirates | The Ageas Bowl, Southampton | 2015 |
| 5-47 | GW Youngson | Scotland XI v Army XI | Raeburn Place, Edinburgh | 1949 |
| 5-51 | TB Sole | Scotland A v Durham Second XI | Burnopfield Cricket Club Ground, Burnopfield | 2017 |
| 5-52 | G Goudie | Scotland A v Nottinghamshire Second XI | Sports Ground, Cleethorpes | 2009 |
| 5-53 | RM Haq | Scotland A v Cavaliers | Bothwell Castle, Uddingston | 2011 |
| 5-56 | J Buchanan | Scotland XI v Australians | Hamilton Crescent, Glasgow | 1882 |
| 5-61 | G Goudie | Scotland A v Lancashire Second XI | Stanley Park, Blackpool | 2008 |
| 5-63 | SJ Chalmers | Scotland A v Durham Second XI | Longhirst Hall Ground, Longhirst | 2009 |
| 5-64 | MJD Allingham | Scotland B v Leicestershire Second XI | Grace Road, Leicester | 1990 |
| 5-66 | AC Evans | Scotland A v Kent and Northamptonshire Second XIs | County Ground, Northampton | 2017 |
| 5-70 | O Henry | Scotland B v Durham University | The Racecourse, Durham | 1987 |
| 5-73 | NR Dyer | Scotland B v Yorkshire Second XI | Park Avenue Cricket Ground, Bradford | 1997 |
| 5-75 | GI Maiden | Scotland B v Marylebone Cricket Club | Denis Compton Oval, Shenley | 2004 |
| 5-78 | W Morton | Scotland B v Central Lancashire League | Nunholm, Dumfries | 1981 |
| 5-79 | SD Weeraratna | Scotland A v Lancashire Second XI | Moss Lane, Alderley Edge | 2007 |
| 5-82 | RM Haq | Scotland A v Lancashire Second XI | Boughton Hall Avenue, Chester | 2012 |
| 5-124 | AN Hunter | Scotland v Australians | Raeburn Place, Edinburgh | 1902 |