| 211 | WA Donald (142) & RG Swan (100) | Scotland v Marylebone Cricket Club | North Inch, Perth | 1981 |
| 208 | CS MacLeod (157*) & RD Berrington (67) | Scotland v Afghanistan | Bulawayo Athletic Club, Bulawayo | 2017/18 |
| 178 | J Aitchison (150) & JAS Taylor (78) | Scotland v Yorkshire | Hamilton Crescent, Glasgow | 1952 |
| 178* | DR Lockhart (53*) & DF Watts (118*) | Scotland v Ireland | Castle Avenue, Dublin | 2004 |
| 170 | MM English (107) & RD Berrington (89) | Scotland v Namibia | Forthill, Dundee | 2024 |
| 166 | CS MacLeod (154) & RD Berrington (54) | Scotland v Papua New Guinea | Amini Park, Port Moresby | 2017/18 |
| 165 | CS MacLeod (103) & PL Mommsen (80*) | Scotland v United Arab Emirates | Raeburn Place, Edinburgh | 2016 |
| 146 | HG Munsey (84*) & RD Berrington (64) | Scotland v Canada | Maple Leaf North-West Ground, King City | 2025 |
| 144 | J Aitchison (190*) & MH Denness (47) | Scotland v Ireland | College Park, Dublin | 1959 |
| 144 | BMW Patterson (83) & G Salmond (89) | Scotland v Ireland | The Village, Malahide, Dublin | 1997 |
| 141 | HK More (134) & BR Hardie (118) | Scotland v Warwickshire | Edgbaston, Birmingham | 1974 |
| 138 | B McMullen (136) & RD Berrington (60) | Scotland v Oman | Bulawayo Athletic Club, Bulawayo | 2023 |
| 137 | JD Martin (88) & W Nicholson (101) | Scotland v Ireland | College Park, Dublin | 1929 |
| 136 | KJ Coetzer (127) & NS Poonia (79) | Scotland v Oman | Walter Milton Oval, University of Witwatersrand, Johannesburg | 2008/09 |
| 133 | KJ Coetzer (91) & GM Hamilton (71) | Scotland v Afghanistan | Willowmoore Park Main Oval, Benoni | 2008/09 |
| 131 | B McMullen (101) & RD Berrington (105) | Scotland v Netherlands | Sportpark Maarschalkerweerd, Utrecht | 2025 |
| 127 | RHE Chisholm (76) & MH Denness (84) | Scotland v Warwickshire | Edgbaston, Birmingham | 1959 |
| 127 | CJO Smith (88) & RA Parsons (53) | Scotland v Namibia | Armour Heights, Toronto | 2001 |
| 127 | CS MacLeod (60) & RD Berrington (60*) | Scotland v Hong Kong | Sheikh Zayed Stadium, Abu Dhabi | 2016/17 |
| 122 | BMW Patterson (68) & G Salmond (69) | Scotland v Ireland | Sandwell Park, West Bromwich | 1997 |
| 122 | GM Hamilton (115) & CJO Smith (59) | Scotland v Ireland | Mannofield Park, Aberdeen | 2008 |
| 122 | MH Cross (66*) & RD Berrington (76) | Scotland v Ireland | The Village, Malahide, Dublin | 2019 |
| 117 | PS Fraser (79) & RGW Tait (59) | Scotland v Ireland | Hamilton Crescent, Glasgow | 1911 |
| 117 | RR Watson (75) & RS Dravid (120*) | Scotland v Somerset | County Ground, Taunton | 2003 |
| 117 | KJ Coetzer (112) & RD Berrington (61) | Scotland v Namibia | Raeburn Place, Edinburgh | 2017 |
| 116 | DR Lockhart (54) & DAJ Rigby (56) | Scotland v Netherlands | Civil Service Cricket Club, Stormont, Belfast | 2002 |
| 116 | KJ Coetzer (74) & RD Berrington (56) | Scotland v Papua New Guinea | Dubai Sports City Stadium, Dubai | 2022 |
| 113 | R Flannigan (102) & KJ Coetzer (62) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 112 | KJ Coetzer (98) & JH Davey (48) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 112 | KJ Coetzer (127) & PL Mommsen (111*) | Scotland v United Arab Emirates | Raeburn Place, Edinburgh | 2016 |
| 111 | MW Machan (61) & MA Leask (58) | Scotland v Netherlands | Sheikh Zayed Stadium, Abu Dhabi | 2013/14 |
| 110 | J Aitchison (74) & GWL Courtenay (69) | Scotland v Derbyshire | Raeburn Place, Edinburgh | 1955 |
| 109 | NS Mitchell-Innes (87) & WR Heggie (44) | Scotland v New Zealanders | Hamilton Crescent, Glasgow | 1937 |
| 109 | RR Watson (83) & DF Watts (50) | Scotland v Bangladeshis | Raeburn Place, Edinburgh | 2004 |
| 108 | DR Lockhart (37) & JC Kent (85) | Scotland v Derbyshire | Raeburn Place, Edinburgh | 2003 |
| 106 | JF Jones (78) & W Nicholson (97) | Scotland v Ireland | Glenpark, Greenock | 1932 |
| 106 | RR Watson (57) & GM Hamilton (79) | Scotland v Bermuda | Ruaraka Sports Club Ground, Nairobi | 2006/07 |
| 105 | HG Munsey (72) & RD Berrington (46*) | Scotland v Italy | Sportpark Westvliet, Voorburg | 2025 |
| 104 | S Sriram (56) & RR Watson (76) | Scotland v Essex | Raeburn Place, Edinburgh | 2004 |
| 104 | B McMullen (68) & RD Berrington (54) | Scotland v Ireland | Raeburn Place, Edinburgh | 2023 |
| 103 | PL Mommsen (102) & KJ Coetzer (56) | Scotland v Namibia | Wanderers Cricket Ground, Windhoek | 2011/12 |
| 101 | DR Lockhart (77*) & G Salmond (46) | Scotland v Ireland | The Village, Malahide, Dublin | 1997 |
| 101 | DR Lockhart (64) & GM Hamilton (115) | Scotland v Canada | Sharjah Cricket Association Stadium, Sharjah | 2004/05 |
| 100 | RR Watson (91) & CJO Smith (42) | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2008 |