| 1 | 301 | IL Philip & AC Storie | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 2 | 229* | DR Lockhart & GN Reifer | Scotland v Earl of Arundel's XI | Arundel Castle Cricket Club Ground, Arundel | 1996 |
| 3 | 211 | WA Donald & RG Swan | Scotland v Marylebone Cricket Club | North Inch, Perth | 1981 |
| 4 | 240 | RR Watson & NFI McCallum | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 5 | 150 | HG Munsey & MH Cross | Scotland v Netherlands | Forthill, Dundee | 2025 |
| 6 | 190 | AK McTavish & BR Tod | Scotland v Ireland | Raeburn Place, Edinburgh | 1936 |
| 7 | 176 | JD Henderson & WA Edward | Scotland v Ireland | North Inch, Perth | 1950 |
| 8 | 187 | JD Henderson & WA Edward | Scotland v Ireland | Whitehaugh Oval, Paisley | 1954 |
| 9 | 107 | NFI McCallum & SJS Smith | Scotland v Afghanistan | Dubai Sports City Stadium, Dubai | 2010/11 |
| 10 | 86 | WH Thorburn & D Chapel | Scotland v Ireland | North Inch, Perth | 1909 |