| 234 | (234) | IL Philip | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1991 |
| 233 | (153*,80*) | GN Reifer | Scotland v Transvaal University | Eben Cuyler Park, Johannesburg | 1991/92 |
| 218 | (108,110) | BR Hardie | Scotland v Marylebone Cricket Club | Mannofield Park, Aberdeen | 1971 |
| 213 | (118,95) | G Salmond | Scotland v Ireland | Forthill, Dundee | 1992 |
| 207 | (125,82) | TB Racionzer | Scotland v Marylebone Cricket Club | Titwood, Glasgow | 1977 |
| 203 | (67,136) | J Kerr | Scotland v Ireland | College Park, Dublin | 1927 |
| 195 | (178*,17) | J Kerr | Scotland v Ireland | College Park, Dublin | 1923 |
| 192 | (89*,103) | AC Storie | Scotland v Marylebone Cricket Club | Lochside Park, Forfar | 1993 |
| 191 | (191) | HG Munsey | Scotland v Netherlands | Forthill, Dundee | 2025 |
| 190 | (190*,0) | J Aitchison | Scotland v Ireland | College Park, Dublin | 1959 |
| 189 | (52,137) | J Kerr | Scotland v Ireland | Raeburn Place, Edinburgh | 1928 |
| 181 | (181,0) | G Salmond | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 181 | (181) | NFI McCallum | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 177 | (161,16) | LC Dudman | Scotland v Warwickshire | Edgbaston, Birmingham | 1956 |
| 176 | (143*,33*) | BR Tod | Scotland v Ireland | Raeburn Place, Edinburgh | 1936 |
| 176 | (93,83) | DF Watts | Scotland v Bermuda | National Stadium, Hamilton | 2008 |
| 175 | (175) | CS MacLeod | Scotland v Canada | Hagley Oval, Christchurch | 2013/14 |
| 171 | (74,97) | A Steele | Scotland v Ireland | Hamilton Crescent, Glasgow | 1968 |
| 171 | (171*) | DF Watts | Scotland v Denmark | New Anniesland, Glasgow | 2006 |
| 167 | (167) | RR Watson | Scotland v Namibia | Mannofield Park, Aberdeen | 2006 |
| 166 | (102*,64*) | AC Storie | Scotland v Ireland | Hamilton Crescent, Glasgow | 1994 |
| 165 | (144*,21) | GL Willatt | Scotland v Warwickshire | Mannofield Park, Aberdeen | 1949 |
| 163 | (61,102*) | RS Weir | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1982 |
| 161 | (146,15) | DF Watts | Scotland v Kenya | Sheikh Zayed Stadium, Abu Dhabi | 2004/05 |
| 157 | (157*) | CS MacLeod | Scotland v Afghanistan | Bulawayo Athletic Club, Bulawayo | 2017/18 |
| 156 | (156) | KJ Coetzer | Scotland v Bangladesh | Saxton Oval, Nelson | 2014/15 |
| 155 | (31,124) | TB Racionzer | Scotland v Warwickshire | Edgbaston, Birmingham | 1976 |
| 155 | (21,134) | IL Philip | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1997 |
| 154 | (118,36) | BR Hardie | Scotland v Warwickshire | Edgbaston, Birmingham | 1972 |
| 154 | (154) | RR Watson | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 154 | (154) | CS MacLeod | Scotland v Papua New Guinea | Amini Park, Port Moresby | 2017/18 |