| 165 | M Azeem Dar (95) & JS Waller (64) | Scotland Under-17s v Northumberland Under-17s | The Wicket, Hipsburn | 2014 |
| 145 | MJ Leonard (113) & G Stewart (37) | Scotland Under-19s v Zimbabwe Under-19s | Ampleforth College, Ampleforth | 1993 |
| 107 | [unknown] & [unknown] | Scotland Under-19s v Gibraltar Under-19s | Sportpark Het Schootsveld, Deventer | 2003 |
| 105 | MM Iqbal (106) & K Hodgson (46) | Scotland Under-17s v Lancashire Under-17s | Bull Hey, Wigan | 2001 |
| 103 | ARI Umeed (118*) & KW Stirling (52) | Scotland Under-19s v Northern Universities Student Club Community Cricketers Elite | Miners Welfare Ground, Blackwell | 2013 |
| 102 | [unknown] & [unknown] | Scotland Under-19s v Abhimanya Cricket Association | Abhimanyu Cricket Academy Ground, Dehra Dun | 2010/11 |
| 100 | Omar Afridi (99) & LH Hill (76) | Scotland Under-17s v Norfolk Under-17s | The Langley, Garboldisham | 2011 |
| 96 | PA Ross (43) & A Bailwal (63) | Scotland Under-19s v Canada Under-19s | The Inch, Dublin | 2011 |
| 95 | [unknown] & [unknown] | Scotland Under-19s v England Under-19s | Civil Service Cricket Club, Stormont, Belfast | 1999 |
| 88 | SJ Cameron (95) & MD Angelini (37*) | Scotland Under-17s v Suffolk Under-17s | Friars Street, Sudbury | 2013 |
| 85 | MM English (44) & CA Cash (55) | Scotland Under-17s v Guernsey Under-17s | New Williamfield, Stirling | 2012 |
| 83 | FRJ Coleman (81) & A Bailwal (39) | Scotland Under-19s v Nepal Under-19s | Anglesea Road, Dublin | 2011 |
| 82 | S Hart (50) & CS MacLeod (68) | Scotland Under-15s v Denmark Under-15s | Herning Ground No 1, Herning | 2004 |
| 79 | SD Weir (66) & MH Cross (35) | Scotland Under-17s v Herefordshire Under-17s | The Parks, Brockhampton | 2010 |
| 78 | N Millar (50) & GI Maiden (34) | Scotland Under-19s v Scottish Universities | Bothwell Castle, Uddingston | 1998 |
| 77 | [unknown] & [unknown] | Scotland Under-19s v Denmark Under-19s | Avion Park Cricket Club, Kempton Park | 1997/98 |
| 75 | HM Locke (134) & K Jacobs (22) | Scotland Under-13s v Denmark Under-13s | Observatory Lane, Rathmines, Dublin | 2002 |
| 74 | Omar Afridi (48) & LH Hill (56) | Scotland Under-15s v Denmark Under-15s | Sportpark Maarschalkerweerd, Utrecht | 2010 |
| 73 | [unknown] & [unknown] | Scotland Under-19s v Yorkshire Academy | Raeburn Place, Edinburgh | 2008 |
| 73 | HR Edwards (53) & PA Ross (24*) | Scotland Under-19s v Australia Under-19s | Boundary Street Oval, Brisbane | 2012 |
| 72 | D Fleming (21) & CS Plomer (68) | Scotland Under-23s v Ireland Under-23s | Cambusdoon, Alloway | 1986 |
| 71* | SW Dalgleish (96*) & R Forsyth (15*) | Scotland Under-18s v Scottish Universities | Bothwell Castle, Uddingston | 2006 |
| 70 | RO Hussain (48) & RT Lyons (22) | Scotland Under-19s v Durham Under-19s | Longhirst Hall Ground, Longhirst | 2003 |
| 70 | K Farid (47) & RD Berrington (23) | Scotland Under-19s v St Thomas' College, Mount Lavinia | St Thomas College Ground, Moratuwa | 2005/06 |
| 69 | BA Townsend (55*) & EGC Stubbs (35) | Scotland Under-19s v Welsh Schools | Hamilton Crescent, Glasgow | 1996 |
| 69 | MJ Petrie (48) & CG Burnett (23) | Scotland Under-19s v Carlton | Grange Loan, Edinburgh | 2009 |
| 68 | JSC Galloway (40*) & CG Burnett (34) | Scotland Under-19s v Leinster | Longhirst Hall Ground, Longhirst | 2008 |
| 65 | [unknown] & [unknown] | Scotland Under-19s v Maharana Pratap Police | Abhimanyu Cricket Academy Ground, Dehra Dun | 2010/11 |
| 65 | JS Waller (62) & SJ Cameron (19) | Scotland Under-19s v Netherlands Under-19s | Grainville, St Saviour | 2015 |
| 64* | SD Gilmour (100*) & KJ Coetzer (27*) | Scotland Under-19s v Namibia Under-19s | Eden Park Outer Oval, Auckland | 2001/02 |
| 64 | KM Smith (83*) & SW McElnea (5) | Scotland Under-13s v Denmark Under-13s | Park Avenue, Dublin | 2005 |
| 64 | ARI Umeed (95*) & A Bailwal (42) | Scotland Under-19s v North West Academy | Senwes Park, Potchefstroom | 2011/12 |
| 64 | FDW McCreath (101) & JW Dickinson (40*) | Scotland Under-15s v Northumberland Under-15s | Kirkhill, Penicuik | 2014 |
| 63 | FRJ Coleman (74*) & PA Ross (26) | Scotland Under-18s v Northern Universities | Derwenthaugh Park, Swalwell | 2010 |
| 62 | SK MacLennan (36) & CS MacLeod (58) | Scotland Under-19s v Ireland Under-19s | Osborne Park, Belfast | 2007 |
| 62 | Q Ashraf (38) & CG Burnett (47) | Scotland Under-19s v United Arab Emirates Under-19s | Longhirst Hall Ground, Longhirst | 2009 |
| 61* | AD Chalmers (25*) & AM Lewis (32*) | Scotland Under-15s v Netherlands Under-15s | Sportpark Het Schootsveld 2, Deventer | 2007 |
| 61 | MJ Petrie (39) & MA Leask (49*) | Scotland Academy v Watsonians | Myreside, Edinburgh | 2010 |
| 60 | [unknown] & [unknown] | Scotland Under-15s v Ireland Under-15s | Inverleith, Edinburgh | 1999 |