| 60 | AG Steel | Scotland v Australians | Raeburn Place, Edinburgh | 1880 |
| 96 | Lord GW Scott | Scotland v Yorkshire | Raeburn Place, Edinburgh | 1887 |
| 68 | G MacGregor | Scotland v Ireland | Raeburn Place, Edinburgh | 1890 |
| 69 | MR Dickson | Scotland v South Africans | Raeburn Place, Edinburgh | 1904 |
| 55* | RGW Tait | Scotland v South Africans | Hamilton Crescent, Glasgow | 1907 |
| 90* | WH Thorburn | Scotland v Ireland | North Inch, Perth | 1909 |
| 50 | J Greive | Scotland v Ireland | Hamilton Crescent, Glasgow | 1911 |
| 79 | PS Fraser | Scotland v Ireland | Hamilton Crescent, Glasgow | 1911 |
| 80 | TP Herriot | Scotland v Indians | Mossilee, Galashiels | 1911 |
| 65 | RE Batson | Scotland v Ireland | Raeburn Place, Edinburgh | 1920 |
| 60 | GWA Alexander | Scotland v Australians | Raeburn Place, Edinburgh | 1921 |
| 54 | AJ Stevenson | Scotland v Ireland | College Park, Dublin | 1925 |
| 51* | JM Fleming | Scotland v Ireland | Glenpark, Greenock | 1926 |
| 69 | AK McTavish | Scotland v Ireland | College Park, Dublin | 1929 |
| 101 | W Nicholson | Scotland v Ireland | College Park, Dublin | 1929 |
| 66 | T Spowart | Scotland v South Americans | Raeburn Place, Edinburgh | 1932 |
| 87 | NS Mitchell-Innes | Scotland v New Zealanders | Hamilton Crescent, Glasgow | 1937 |
| 59 | J Aitchison | Scotland v Indians | Myreside, Edinburgh | 1946 |
| 51 | IJM Lumsden | Scotland v Ireland | Glenpark, Greenock | 1946 |
| 78 | JAS Taylor | Scotland v Yorkshire | Hamilton Crescent, Glasgow | 1952 |
| 69 | GWL Courtenay | Scotland v Derbyshire | Raeburn Place, Edinburgh | 1955 |
| 96 | RW Young | Scotland v Ireland | Glenpark, Greenock | 1962 |
| 57 | TB Racionzer | Scotland v Ireland | Sydney Parade, Dublin | 1965 |
| 50 | HK More | Scotland v Cambridge University | FP Fenner's Ground, Cambridge | 1966 |
| 51 | DER Stewart | Scotland v Warwickshire | Edgbaston, Birmingham | 1969 |
| 59* | DJ Simpson | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1984 |
| 61* | K Scott | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 1984 |
| 79 | MJ Smith | Scotland v Ireland | Lodge Road, Coleraine | 1987 |
| 55* | MJD Allingham | Scotland v England Amateur XI | Eastwood Gardens, Gateshead | 1991 |
| 55 | DG Wright | Scotland v Middlesex Cricket Board | John Walker's Ground, Southgate | 2001 |
| 81 | RE More | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2002 |
| 59 | CJ Borgas | Scotland v Warwickshire | Edgbaston, Birmingham | 2009 |
| 80 | LR Butterworth | Scotland v Marylebone Cricket Club | Lord's Cricket Ground, St John's Wood | 2011 |
| 87 | MA Jones | Scotland v Ireland | ICC Cricket Academy Ground, Dubai | 2017/18 |
| 54* | CJ Tear | Scotland v United Arab Emirates | Dubai Sports City Stadium, Dubai | 2023/24 |
| 107 | MM English | Scotland v Namibia | Forthill, Dundee | 2024 |