| 240 | RR Watson (154) & NFI McCallum (181) | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 224* | DA Lewis (113*) & GD Harrison (105*) | Ireland v Scotland | Hamilton Crescent, Glasgow | 1994 |
| 222 | IJ Anderson (147) & AJ O'Riordan (117) | Ireland v Scotland | Hamilton Crescent, Glasgow | 1976 |
| 177 | RR Watson (167) & CJO Smith (70) | Scotland v Namibia | Mannofield Park, Aberdeen | 2006 |
| 172 | W Bardsley (149) & C Kelleway (64) | Australians v Scotland | Raeburn Place, Edinburgh | 1912 |
| 165 | G Salmond (181) & JG Williamson (55) | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 159 | A Jacobs (85) & AM van den Berg (94) | South Africa Academy v Scotland | Forthill, Dundee | 1999 |
| 153 | Saqib Ali (71*) & Khurram Khan (74) | United Arab Emirates v Scotland | Cambusdoon New Ground, Alloway | 2007 |
| 144 | TJ MacDonald (132) & TGB McVeagh (65) | Ireland v Scotland | Raeburn Place, Edinburgh | 1928 |
| 142 | BE Congdon (176*) & JR Reid (70) | New Zealanders v Scotland | Hamilton Crescent, Glasgow | 1965 |
| 139 | B Zuiderent (78) & LP van Troost (71) | Netherlands v Scotland | Mannofield Park, Aberdeen | 2004 |
| 138 | MJK Smith (90) & TW Cartwright (85) | Warwickshire v Scotland | Raeburn Place, Edinburgh | 1963 |
| 132 | HGH Mulholland (149) & RJH Lambert (103*) | Ireland v Scotland | Hamilton Crescent, Glasgow | 1911 |
| 119 | RS Weir (65) & ABM Ker (58) | Scotland v Ireland | Myreside, Edinburgh | 1982 |
| 114 | G Salmond (118) & AB Russell (33) | Scotland v Ireland | Forthill, Dundee | 1992 |
| 113 | G Salmond (95) & AB Russell (29*) | Scotland v Ireland | Forthill, Dundee | 1992 |
| 112* | B Zuiderent (68*) & LP van Troost (46*) | Netherlands v Scotland | Mannofield Park, Aberdeen | 2004 |
| 111 | SJ Baard (88) & JN Frylinck (158) | Namibia v Scotland | Cambusdoon New Ground, Alloway | 2017 |
| 104 | WP Hone (92) & AC Bateman (52) | Ireland v Scotland | Raeburn Place, Edinburgh | 1913 |
| 104 | AR Dunlop (150) & MA Gillespie (34) | Ireland v Scotland | Cambusdoon New Ground, Alloway | 2000 |
| 102 | RB Minnett (65*) & W Bardsley (45) | Australians v Scotland | Raeburn Place, Edinburgh | 1912 |
| 98 | TB Racionzer (58*) & R Ellis (35) | Scotland v Ireland | Glenpark, Greenock | 1972 |
| 97 | RG Broadbent (106) & DW Richardson (36*) | Worcestershire v Scotland | Hamilton Crescent, Glasgow | 1955 |
| 94 | FA Lowson (166) & JV Wilson (45) | Yorkshire v Scotland | Hamilton Crescent, Glasgow | 1953 |
| 94 | Waqar Hasan (72) & MEZ Ghazali (35) | Pakistanis v Scotland | Raeburn Place, Edinburgh | 1954 |
| 90 | RJH Lambert (63) & DR Pigot (51) | Ireland v Scotland | Hamilton Crescent, Glasgow | 1922 |