| 176 | BA Barnett (92) & AF Kippax (90*) | Australians v Scotland | Raeburn Place, Edinburgh | 1934 |
| 151 | JN Frylinck (158) & C Viljoen (77) | Namibia v Scotland | Cambusdoon New Ground, Alloway | 2017 |
| 130 | JM Allan (58*) & D Barr (86) | Scotland v Marylebone Cricket Club | Hamilton Crescent, Glasgow | 1967 |
| 126 | [unknown] & [unknown] | New Zealanders v Scotland | Hamilton Crescent, Glasgow | 1949 |
| 123 | Shaiman Anwar (78) & Rameez Shahzad (74*) | United Arab Emirates v Scotland | Cambusdoon New Ground, Alloway | 2016 |
| 120 | [unknown] & [unknown] | Ireland v Scotland | Raeburn Place, Edinburgh | 1928 |
| 118 | JA Prior (87) & GD Harrison (32) | Ireland v Scotland | Titwood, Glasgow | 1984 |
| 115 | WTS Porterfield (118) & AR White (55) | Ireland v Scotland | Mannofield Park, Aberdeen | 2009 |
| 114 | G Salmond (181) & MJD Allingham (50*) | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 114 | DA Lewis (71) & PG Gillespie (53) | Ireland v Scotland | Boghall, Linlithgow | 1996 |
| 109* | RJH Lambert (103*) & WW Meldon (42*) | Ireland v Scotland | Hamilton Crescent, Glasgow | 1911 |
| 104 | [unknown] & [unknown] | New Zealanders v Scotland | Hamilton Crescent, Glasgow | 1969 |
| 91 | MC Henriques (59*) & AC Agar (56) | Australia A v Scotland | Raeburn Place, Edinburgh | 2013 |
| 80 | J Aitchison (61) & W Nichol (93) | Scotland v Pakistanis | Raeburn Place, Edinburgh | 1954 |
| 79 | DR Martyn (60*) & CR Miller (44) | Australia A v Scotland | Raeburn Place, Edinburgh | 1998 |
| 77 | IL Philip (110) & JG Williamson (49) | Scotland v Ireland | Boghall, Linlithgow | 1996 |
| 76 | BMW Patterson (100) & MJ Smith (40) | Scotland v Ireland | Nunholm, Dumfries | 1988 |
| 75 | FM Quinn (140) & RJ Barnes (48) | Ireland v Scotland | Glenpark, Greenock | 1946 |
| 73 | NFI McCallum (181) & RM Haq (37) | Scotland v Netherlands | Mannofield Park, Aberdeen | 2007 |
| 71 | JF Jones (54) & AK McTavish (109) | Scotland v South Americans | Raeburn Place, Edinburgh | 1932 |
| 70 | SF Burger (69) & G Snyman (41) | Namibia v Scotland | Mannofield Park, Aberdeen | 2006 |