| Extras |
| 103 | Durham Second XI v Scotland B | Longhirst Hall Ground, Longhirst | 1999 |
| 87 | Durham Second XI v Scotland B | Denton Bank, Benwell Hill | 1993 |
| 73 | Yorkshire Second XI v Scotland A | The Playing Field, Stamford Bridge | 2007 |
| 64 | Northamptonshire Second XI v Scotland Development XI | County Ground, Northampton | 2013 |
| 62 | Derbyshire Second XI v Scotland A | Christchurch Meadows, Belper | 2008 |
| 61 | Scotland Development XI v Marylebone Cricket Club | New Williamfield, Stirling | 2013 |
| 61 | Lancashire Second XI v Scotland A | Stanley Park, Blackpool | 2014 |
| 60 | Leicestershire Second XI v Scotland A | Wilson Field, Oakham School | 2007 |
| 59 | Gloucestershire Second XI v Scotland Development XI | County Ground, Bristol | 2013 |
| 58 | Denmark Under-23s v Scotland Under-23s | Anglesea Road, Dublin | 2006 |
| 57 | Durham Second XI v Scotland B | Grangefield Road, Stockton-on-Tees | 1995 |
| 55 | Lancashire Second XI v Scotland B | Old Trafford, Manchester | 1987 |
| 54 | Durham Second XI v Scotland XI | Eastwood Gardens, Gateshead | 2001 |
| 54 | Kent and Northamptonshire Second XIs v Scotland A | County Ground, Northampton | 2017 |
| 52 | Gloucestershire Second XI v Scotland A | County Ground, Bristol | 2014 |
| 49 | Scotland A v Marylebone Cricket Club | Cambusdoon New Ground, Alloway | 2009 |
| 49 | Northamptonshire Second XI v Scotland A | West Lodge Park, Desborough | 2012 |
| 47 | Scotland XI v Scottish National Cricket League Select XI | Goldenacre, Edinburgh | 2005 |
| 47 | Lancashire Second XI v Scotland A | Boughton Hall Avenue, Chester | 2012 |
| 46 | Nottinghamshire Second XI v Scotland A | Caythorpe Road, Caythorpe | 2007 |
| 46 | Bath v Scotland A | North Parade, Bath | 2018 |
| 44 | Leicestershire Second XI v Scotland A | Bath Grounds, Ashby-de-la-Zouch | 2010 |
| 43 | Durham Second XI v Scotland A | Emirates Riverside, Chester-le-Street | 2018 |
| 42 | Namibia v Scotland XI | Trans Namib Ground, Windhoek | 2000/01 |
| 41 | Durham University v Scotland B | The Racecourse, Durham | 1995 |
| 41 | Durham v Scotland XI | Ropery Lane, Chester-le-Street | 2002 |
| 41 | Ireland Under-23s v Scotland Under-23s | The Vineyard, Dublin | 2006 |
| 41 | Lancashire Second XI v Scotland A | Moss Lane, Alderley Edge | 2013 |
| 40 | Durham University v Scotland B | The Racecourse, Durham | 1985 |
| 40 | Derbyshire Second XI v Scotland A | The Copper Yard, Denby Village | 2007 |
| 40 | Leicestershire Second XI v Scotland A | Fairfield Road, Market Harborough | 2009 |
| 40 | Northamptonshire Second XI v Scotland A | Campbell Park, Milton Keynes | 2018 |